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PUBLIC HEALTH ASSESSMENT

TINKER AIR FORCE (SOLDIER CR/BUILDING 3001)
MIDWEST CITY, OKLAHOMA COUNTY, OKLAHOMA


PUBLIC HEALTH IMPLICATIONS

Toxicologic Evaluation

Contaminants disposed (released) into the environment are a public health concern if exposures to the contamination could result in adverse health effects. However, for adverse health effects to occur from contamination, two principle criteria must be met: The exposure pathway must be completed, and the exposure concentration must be sufficient to cause adverse health effects. A release of a contaminant to the environment does not always result in exposure. People are exposed to a contaminant only if they come in contact with it. For example, exposure may occur by breathing, eating, or drinking a substance containing the contaminant, or by having skin contact with a contaminant or a substance containing the contaminant. Several factors determine the type and severity of health effects associated with exposure to a contaminant: exposure concentration (how much); the frequency and/or duration of exposure (how long); the route or pathway of exposure (breathing, eating, drinking, or skin contact); and the multiplicity of exposure (combination of contaminants). Once exposure takes place, characteristics such as age, sex, nutritional status, genetics, lifestyle, and health status of the exposed individual influence how the individual absorbs, distributes, metabolizes (processes), and excretes (eliminates) the contaminant. Together, those factors and characteristics determine the health effects that may result from exposure to a contaminant. ATSDR considers the previously described physical and biologic characteristics when evaluating site-specific exposures.

Toxicological profiles prepared by ATSDR summarize chemical-specific toxicologic and adverse health effects information. Health guidelines, such as ATSDR's minimal risk level (MRL) and EPA's reference dose (RfD) and cancer slope factor are included in the toxicological profiles. Those guidelines are used by ATSDR public health professionals to determine an individual's potential for developing adverse health effects from exposure to a hazardous substance.

Health guidelines, such as MRLs and RfDs, provide a basis for comparing estimated exposures with concentrations of contaminants in different environmental media (soil, air, water, and food) to which people might be exposed. Health guidelines are generally considered to have a degree of uncertainty; the values are calculated from scientific studies using standardized uncertainty factors. Therefore, health guidelines should not be considered strict scientific boundaries between toxic and nontoxic levels.

An MRL is defined as an estimate of the daily human exposure to a contaminant that is likely to be without an appreciable risk of adverse noncancerous health effects over a specified duration of exposure (acute, 1-14 days; intermediate, 15-365 days; chronic, more than 365 days). Currently, MRLs are not derived for dermal exposure. EPA's RfD and RfC are estimates of the daily exposure of the human population, including sensitive subpopulations, that is likely to be without appreciable risk of adverse noncancerous health effects during a lifetime (70 years). The methods used to derive MRLs and RfDs do not consider information about cancer; therefore, these guidelines do not imply anything about the presence, absence, or level of cancer risk. The available guidelines for cancer-causing substances include the weight-of-evidence of carcinogenicity and the cancer slope factor. The weight-of-evidence classification reflects a judgement of the likelihood that a chemical is a human carcinogen. EPA's cancer slope factor is used to determine the number of excess cancers expected from exposure to a contaminant.

Using the available health guidelines and scientific information, ATSDR determines the likelihood that an adverse health effect, cancerous and/or noncancerous, will occur as a result of exposure to contamination. Cancerous and noncancerous health effects occur via different biological mechanisms, and therefore, are evaluated separately using different health guidelines and scientific information. If either cancerous or noncancerous health outcomes are expected to occur as a result of exposure to contaminants, the exposure is determined to be of public health concern.

To link a site's exposure potential with health effects that may occur under site-specific conditions, ATSDR estimates exposure to site contaminants from ingestion and inhalation of different environmental media.48 The following relationship is used to determine the estimated exposure to a site contaminant:

Routes of exposure identified by ATSDR's public health evaluation are through private drinking water wells, base supply wells, the sediment and surface waters of East Soldier Creek, the sediment of West Soldier Creek and Crutcho Creek, and air in the vicinity of the IWTP.

To estimate exposures to contaminated drinking water, ATSDR used standard intake rates of 2 liters (L)/day for adults and 1 L/day for children. Past exposures through ingestion were estimated assuming a 40 year exposure period (based on when the base was first established). This is a very conservative exposure duration and is protective of people who have lived in this neighborhood since the 1950s. To estimate exposures to contaminated sediment and soil, ATSDR used standard soil ingestion rates of 50 mg/day for adults and 100 mg/day for children. Standard body weights for adults and children are 70 kg and 10 kg, respectively. The maximum contaminant concentration detected in a specific medium at the point of exposure was used to determine the estimated exposure; using the maximum concentration results in an evaluation most protective of public health. When unknown, the biologic absorption from an environmental medium, such as water, is assumed to be 100%.

To evaluate environmental exposures to contaminated surface water and sediment, on- and off-site exposure scenarios were developed. ATSDR assumed that children come in contact with the creeks (play/wade/swim) 90 days a year [five days a week during the summer (June-August) and once a week during the fall and spring]. Standard ingestion rates do not exist for incidental ingestion of surface water while playing in streams. An ingestion rate of 50 ml/day for children was used to estimate incidental ingestion of surface water while playing in the creeks.78 This value is representative of incidental ingestion of water during swimming activities.

ATSDR assumed workers on base were exposed to contaminated sediments and surface waters via ingestion and dermal contact 5 days a week, 50 weeks a year for 20 years (common worker scenario). This scenario is conservative for most workers on base, most will actually be exposed less frequently. ATSDR has identified no job on base that would result in daily exposure to sediments. However, this approach includes any future scenario for workers.

People have been exposed to multiple contaminants as a result of exposure to contaminated water, sediments, and air. However, few data are available on the health effects of exposure to multiple contaminants. Effects of exposure to multiple contaminants can be additive, synergistic (greater than the sum of single contaminant exposures), or antagonistic (less than the sum of single contaminant exposures). Because of the many uncertainties surrounding exposure to multiple contaminants, ATSDR's evaluation of multiple exposure is limited.

Site-specific contaminant exposures for each pathway are discussed below. Additional toxicologic information is provided in Appendix H for contaminants that are determined to be of public health concern.

Base Supply Well Pathway

In September - November 1983, VOCs were detected in base supply wells 18 and 19. Concentrations in well 18 were significantly elevated (Table 2). In response to the sampling results, the Air Force removed the wells from the base supply system in 1984. Therefore, on-base exposure to VOCs occurred prior to 1984. Contaminants detected included trichloroethylene, tetrachloroethylene, 1,1,2-trichloroethane, 1,1-dichloroethane, and 1,2-dichloroethane.

ATSDR was unable to determine the concentrations people were exposed to, duration of the exposure, or population that was exposed. It is likely that the concentrations that people were exposed to were less that those detected in well 18 (1642 ppb, TCE). Water is pumped into the distribution system with holding tanks positioned along the system. Therefore, the addition of uncontaminated water from other base supply wells would dilute the concentrations of contaminants in the water delivered at the taps. However, it is likely that even following dilution people were exposed to concentrations of TCE above the MCL of 5 ppb. An estimate of how long base wells 18 and 19 were contaminated prior to closure in 1984 is difficult to determine. Sampling was not required prior January 1988 (Safe Drinking Water Act). Therefore, sampling results are not available to determine when the wells became contaminated. Water usage within the system is somewhat localized, water pumped into the distribution system from a supply well is largely used by patrons within close proximity of the holding tank for that well.79 Therefore, people working on base in areas near well 18 are the persons with the highest potential for past exposure. Persons in these areas would have been exposed through ingestion of water, inhalation of the volatilized contaminants, and dermal contact with the water. ATSDR considers this past exposure to be of public health concern because the concentrations in well 18 were significantly elevated above drinking water standards and the contaminants detected are classified as probable carcinogens. These exposures are discussed in the 1988 Public Health Assessment (Appendix A). Since 1984, VOCs above drinking water standards have not been detected in the base supply wells that have been in use.

Lead, arsenic, and selenium were detected (1986-1990) above ATSDR health guidelines for chronic exposure in base supply wells 13 and 14 (Table 3). The base was not out of compliance with regulatory values at the time of analysis. But with new available scientific information, exposures to these concentrations are potentially of concern today. Therefore, the metals were included as contaminants of concern in Table 3. However, based on a worker exposure scenario, adverse health effects are not expected to occur as a result of exposure to the concentrations of lead, arsenic, or selenium detected in the base supply wells. Children, the most sensitive population, are not expected to be exposed to water from these supply wells. The drinking water at the on-base Child Development Center is provided by the base distribution system and is a mixture of municipal and base water. Current sampling has shown that the mixture of municipal and base water supplied to the Child Development Center is in compliance with the Safe Drinking Water Act.

Private Well Pathway

Exposure to contaminants in private well water occurred via ingestion, inhalation, and dermal contact. VOCs detected in private wells at concentrations above health comparison values include TCE, PCE, benzene, and 1,2-DCA. Barium, was also detected in a private well above the health comparison value. This sampling data is presented in Table 4. The ingestion route of exposure ceased when residents were supplied bottled water for drinking and cooking. However, because well water was used for other household purposes, such as showers and laundry, exposures through inhalation of the volatilized contaminants and dermal contact continued until the homes were provided municipal water.

Exposure via inhalation of VOCs volatilized from domestic use of water (showering, washing, cooking, etc) is expected to be at least equivalent to that from ingestion.80 Dermal absorption of VOCs vapor through the skin is negligible. However, absorption of VOCs solubilized in water may be significant.81 Therefore, total daily exposure (ingestion, inhalation, and dermal contact) is expected to be approximately two to three times the estimated daily ingestion exposure.

TCE was detected at a maximum concentration of 13.8 ppb in private wells. Using the maximum detected concentration, the daily estimated exposure to TCE from past ingestion of contaminated well water is 0.0004 mg/kg/day for adults and 0.0014 mg/kg/day for children. Assuming a total exposure (ingestion, inhalation, and dermal contact) of three times the daily estimated exposure from ingestion (most conservative estimate), total exposure was 0.0012 mg/kg/day for adults and 0.0042 mg/kg/day for children. The MRL for intermediate exposure (daily exposures of less than one year's duration) is 0.7 mg/kg/day.82 A health guideline for chronic TCE exposure has not been developed.

The estimated exposure for children and adults is less than the intermediate-MRL. Therefore, adverse noncancerous health effects are not expected to result from intermediate exposures to TCE-contaminated drinking water in neighborhoods near Tinker. It is unlikely that chronic exposures to contaminated water near Tinker would result in adverse noncancerous health effects. Studies of animals have indicated that chronic TCE exposure may result in adverse developmental, heart, kidney, or liver effects.82 However, exposures in those studies were thousands of times greater than the expected exposures of people living near Tinker.

Populations that may be susceptible to chronic TCE exposure include people who consume alcohol, people treated with disulfiram, and people who have liver dysfunction or heart conditions. Fetuses in the first trimester (first three months of pregnancy) may be a population of particular concern. Epidemiologic studies have associated chronic exposure to TCE-contaminated drinking water (6-239 ppb) with congenital heart defects.83 The significance of this finding is questionable because of the possibility that the women were exposed to multiple chemicals. Congenital heart defects resulting from TCE exposure also have been reported in animals.84,85

There is some uncertainty as to the carcinogenicity of TCE. EPA has classified TCE as a probable human carcinogen by way of ingestion.55,82 However, the cancer classification and slope factor are currently being reviewed by EPA. The National Toxicology Program does not consider TCE a carcinogen.82 Therefore, the evaluation of cancer risk as a result of exposure to TCE is questionable. Using the cancer slope factor, a small increase in cancer risk may be expected as a result of exposure to TCE-contaminated water. Only people who were exposed for over five years at the maximum concentrations detected are expected to have an increased risk of developing cancer as a result of the exposure. Therefore, an increase in cancer rates due to TCE exposure would be undetected in the population near Tinker because only a small number of people were exposed to the maximum concentrations, the increased cancer risk is small, and because the average cancer incidence in an area has a number of causes.

PCE was detected in private wells at a maximum concentration of 20.1 ppb. Assuming a total exposure of three times the daily estimated exposure from ingestion (most conservative estimate), total exposure would be 0.002 mg/kg/day for adults and 0.006 mg/kg/day for children. The chronic RfD for PCE is 0.01 mg/kg/day which is greater than the estimated exposures.86 Therefore, adverse noncancerous health effects in children or adults as a result of exposure to PCE-contaminated water are not expected to occur.

The EPA has classified tetrachloroethylene as a probable human carcinogen through ingestion and inhalation based on epidemiological studies of workers exposed to PCE and animals studies. The National Toxicological Program considers PCE to be a reasonably anticipated carcinogen. Based on risk calculations, there is no increased cancer risk from exposure to PCE at the concentrations detected.

Benzene was detected at a maximum concentration of 21 ppb (October 8, 1991) in one of two supply wells at the Evergreen Trailer Park. However, the contaminated well was not being used as a potable source of water when the contamination was detected.87 The well may have been used for other nonpotable purposes, however, and people may have been exposed by dermal contact and inhalation of volatilized contaminants. Three days after the contamination was detected, bottled water was provided as a preventive measure to the trailer park. The length of time that people were exposed at the trailer park cannot accurately be determined. However, the exposure duration was less than 16 months because contamination was not detected during analysis of samples collected from both wells in June 1990.87

The MCL (long term exposure) for benzene is 5 ppb. This regulation is based on preventing leukemia.88 The maximum concentration detected in the supply well was greater than the MCL. However, the people were not using the water as the potable source for the trailer park. The level for short-term exposure (ten days) is 235 ppb for children.

Using the maximum concentration detected and assuming that people were drinking the water (the worst-case scenario), the estimated exposures from ingestion of water are 0.002 mg/kg/day for children and 0.0006 mg/kg/day for adults. Total estimated exposures are 0.006 mg/kg/day and 0.0018 mg/kg/day for children and adults, respectively. Animal studies have reported a no-observed-adverse effect level (NOAEL) at 1 mg/kg/day. The NOAEL is more than a hundred-fold greater than the estimated exposures of a worst-case scenario. Therefore, it is unlikely that noncancerous adverse health effects would occur as a result of exposures to benzene in the trailer park well.

Benzene can enter your body through the skin. However, studies regarding human dermal exposure to benzene were not reported.88 Adverse dermal effects have been observed in laboratory animals following skin contact with undiluted benzene. However, dermal contact with benzene similar to the concentrations detected in private wells near Tinker should not be of public health concern.

EPA estimates that exposure to 10 ppb benzene in drinking water over a lifetime could increase the risk of cancer by one case for every 100,000 exposed persons.89 The DHHS, IARC, ACGIH, OSHA, and WHO also consider benzene to be a human carcinogen. People at the Evergreen Trailer Park were not using the water as a potable source of water and nonpotable exposures were less than 16 months in duration. Therefore, adverse cancerous health effects are not expected to occur as a result of the exposures. Benzene was detected at 9.8 ppb in one private well being used for drinking water. The exposure duration for this well was not determined. Longterm exposure to benzene at this concentration in drinking water may increase the risk of developing cancer. Benzene was detected at 1.8 ppb in one additional private well, but adverse health effects are not expected as a result of the exposure.

A maximum concentration of 46 ppb of 1,2-dichloroethane (1,2-DCA) was detected in a private well northeast of Tinker. 1,2-DCA was detected in three other wells but, the concentrations were much lower; 8.54 ppb, 2.38 ppb, and < 1 ppb. The concentrations of 1,2-DCA that cause particular non-cancerous adverse health effects in humans are unknown.91 Most of the effects seen in humans have occurred after accidental ingestion of large amounts or after exposure via inhalation to unknown levels of 1,2-DCA.

Health-based drinking water advisory levels are available. For children, the longer-term health advisory (CLHA) value is 740 ppb and for adults it is 2600 ppb. Since the maximum concentration of 1,2-DCA detected is considerably less than the health advisories, past exposures to 1,2-DCA via ingestion are not expected to result in noncancerous adverse health effects.

People can be exposed to 1,2-DCA through the skin. Dermatitis may result from prolonged skin contact with 1,2-DCA; however, concentrations at which this occurred were not reported.90 Also, skin lesions in animals have resulted from dermal exposure to 1,2-DCA and it is likely that highly concentrated solutions of 1,2-DCA would have this effect on humans, too.91 Because highly concentrated 1,2-DCA levels are not expected to come from private well water near Tinker, no adverse dermal effects are expected.

Based on animal studies, the EPA has classified 1,2-DCA as a probable human carcinogen via inhalation and ingestion.89 Using the EPA cancer slope factor, an increased risk of developing cancer is expected as a result of exposure to the maximum concentration of 1,2-DCA detected. However, adverse cancerous health effects are not expected as a result of exposure to the concentrations detected in the other three wells.

Barium was detected in a private well at a maximum concentration of 1220 ppb. Barium concentrations in groundwater supplies sometimes will exceed EPA's MCL of 1000 ppb; this may be due to leaching and erosion of barium from sedimentary rocks.92

The estimated exposure through ingestion is 0.034 mg/kg/day for adults and 0.122 mg/kg/day for children. The estimated dose for children exceeds the oral RfD of 0.07 mg/kg/day. However, barium is poorly absorbed by the gastrointestinal (GI) tract and it is estimated that the GI absorption of barium is less than five percent.92

Adverse health effects have not been reported following exposure to barium concentrations similar to those detected in the private well. Most of the data on health effects of barium come from studies in which a small number of people were exposed to fairly large amounts of barium for a short time.92 Information is currently being collected to find out if long-term exposure to low levels of this metal causes any health problems.92

Barium is not expected to volatilize from water during household use. Thus, adverse health effects are not expected to result from inhalation of barium from private wells near Tinker. Health effects have been shown to occur from occupational exposure to high but unknown barium levels in air.92 However, these exposures occur in occupational settings with extreme temperatures. Barium has a vapor pressure of 10 mmHg at 1049 degrees Fahrenheit.

At pH levels of 9.3 or below (pH range for private well water was 6.0 - 7.0), the barium ion (Ba2) is the predominant species.66 Often the water will contain enough sulfate that a barium ion concentration of more than 1,000 - 1,500 ppb is not maintained in solution. Most barium compounds are highly polar (dissociates to form ions in water); polar compounds are generally poorly absorbed through the skin.93 Therefore, exposure to barium at the concentrations detected at Tinker is not expected to result in significant dermal uptake of the chemical. No adverse health effects are expected to result from skin contact with barium in private well water.

Barium is not known to cause cancer in humans through any route of exposure.

Sediment Pathway--East Soldier Creek

There were several sampling locations of sediment along East Soldier Creek. ATSDR focused on locations E09, E10, and E11 because of the potential for human exposure in those areas (Figure 7). Contaminants detected above health comparisons values at the above locations are evaluated in relationship to the exposure expected at that location. The public health significance of exposure to the maximum concentration detected is also reported. The location and maximum concentration detected in sediments in East Soldier Creek are listed in Table 6.

Cadmium was detected at a concentration of 10.5 ppm in sediment in the area behind the Evergreen Trailer Park (sample E11). Based on the most likely exposure scenario described previously, the estimated exposure for children playing along the creek is 0.000004 mg/kg/day from incidental ingestion of sediment. This value is one hundred-fold less than the oral MRL for cadmium, a daily lifetime exposure guideline. Even daily exposure to the concentrations of cadmium detected in sediment would not result in exposures greater than the MRL. Moreover, most ingested cadmium passes through the GI tract without being absorbed.94 Therefore, exposure to cadmium in the sediments of East Soldier Creek in this area are not expected to result in adverse health effects.

Cadmium was detected at 324 ppm at sampling site E09, an outfall of Building 3001. This was the maximum detected concentration in East Soldier Creek. Assuming on-base workers are exposed five days a week, the estimated exposure is ten fold less than the MRL. Therefore, oral exposure to cadmium in the sediments near the outfalls are not expected to result in adverse health effects.

Daily exposure of children to the maximum concentration of 324 ppm may result in a slight increased risk for adverse health effects. However, it is very unlikely that children would be exposed daily to the maximum concentration because the location is not accessible to children and children are not expected to play in the creek on a daily basis.

Very little cadmium enters the body through skin, so dermal contact with cadmium contaminated sediments at the above sites is not expected to result in adverse health effects.94

Guidelines to estimate cancer risk from oral exposure to cadmium are not available because studies of human ingestion of cadmium are inadequate to assess carcinogenicity.55 A few studies of cancer rates among people exposed to cadmium orally have been reported. No significant increase in cancer rates was found. Overall, there is little evidence of an association between oral exposure to cadmium and increased cancer rates in people. However, the studies are inconclusive. The EPA has classified cadmium as a probable human carcinogen by inhalation based on limited evidence from occupational epidemiologic and laboratory animal studies. However, exposure to cadmium by inhalation was not identified as a route of exposure for this site.

In the laboratory analysis for beryllium, the sample detection limit was greater than the CREG. Beryllium concentrations were, therefore, reported as the detection limit. This means the precise concentrations in the samples are unknown, but the actual concentrations are less than or equal to the reported value. The reported values were 0.62 ppm at E09, 0.31 ppm at E10 (Douglas Boulevard bridge), and 0.68 ppm at E11 (Evergreen Trailer Park). The maximum concentration reported was 0.77 ppm at E12.

Using the reported value (a conservative estimate), no increased cancer risk is expected from exposure to beryllium via incidental ingestion of sediment in East Soldier Creek. The estimated exposures are also below health guidelines for noncancerous adverse health effects. Therefore, adverse health effects are not expected to result from incidental ingestion of sediments containing beryllium.

Very little beryllium is expected to enter the body from skin contact with contaminated soil. Thus, dermal contact with beryllium at the above sites is not expected to result in adverse health effects.95

Several PAHs, both carcinogenic and noncarcinogenic, were detected in East Soldier Creek sediment above health comparison values. Carcinogenic PAHs detected include: benz(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, pyrene, and indeno(1,2,3-cd)pyrene. Noncarcinogenic PAHs detected include: acenaphthene, phenanthrene, and benzo(g,h,i)perylene.

All noncarcinogenic PAHs detected in the sediments at E09, E10, and E11 are over a thousand-fold less than risk-based concentrations for residential soil.96 From all the sampling locations on East Soldier Creek, E03 had the maximum concentration of noncarcinogenic PAHs. However, concentrations at E03 were more than 300-fold less than the risk-based concentrations. Therefore, noncancerous adverse health effects are not expected as a result of exposure to sediments in East Soldier Creek.

A method using toxicity equivalency factors (TEFs) has been developed for evaluating carcinogenic PAHs. Benzo(a)pyrene is the more carcinogenic of the PAHs and is used as the reference compound in this type of evaluation. The method is based on each compounds relative potency to the potency of benzo(a)pyrene. The other carcinogenic PAH concentrations are made equivalent to the reference compound, benzo(a)pyrene.97

The TEF adjusted total concentrations of carcinogenic PAHs are 1.7 ppm at E09, 2.9 ppm at E10, and 0.2 ppm at E11. Based on a cancer slope factor of 5.8 (mg/kg/day)-1, cancerous health effects from incidental ingestion exposure to sediment at locations E09, E10, and E11 are not of public health concern. Daily exposure to sediments at location E03 (location with maximum adjusted concentration of 16.6 ppm) may result in a slight increase in cancerous effects. However, daily exposure is not expected at this location and infrequent exposure is not a concern.

Chronic dermatitis and hyperkeratosis have been seen in workers exposed chronically to substances that contain PAHs. However, those exposures have been at much greater concentrations than those at Tinker. Absorption of PAHs from dermal contact with soil is expected to be minimal. Studies using human skin reported only 3% permeation of an applied dose of benzo(a)pyrene after 24 hours.98 Thus, skin contact with PAH-contaminated sediment at Tinker is not expected to cause adverse noncancerous health effects.

The maximum concentration of lead detected in sediment was 586 ppm at location E09. Exposure to sediment with this concentration of lead is not of public health concern for workers. Daily exposure of children to sediment at this location in the creek may be of slight concern. However, in general, children are not expected to be exposed to sediments in the creek on a daily basis. In addition, exposure of children at this location is not expected to occur.

Chromium was detected at 1190 ppm at E09 (maximum detected in East Solider Creek). The chromium was not speciated (chromium III vs. chromium VI). The EPA Region III residential soil risk-based concentration is 390 ppm and 78000 ppm for chromium VI and III, respectively.96 Even if the contaminant is 100% chromium VI, the more toxic form, this level is not a concern for exposure to workers or infrequent exposure of children. However, daily exposure of children may be of public health concern if the contaminant is 100% chromium VI. The typical ratio of chromium discharged from the IWTP is one part chromium VI to five parts chromium III.67 In addition, chromium VI can be reduced to chromium III by organic matter in water.99 Therefore, it is unlikely that adverse health effects would result from daily exposure of children to the sediment.

Some contaminants were detected at locations other than E09, E10, and E11. These contaminants and location of maximum detection include the following: tetrachloroethylene (E03), dibenzofuran (E03), DI-n-butylphthalate (E08), magnesium (E02), and manganese (E02). These contaminants were detected in locations that were determined not to be primary points of exposure. Exposures at these locations would be infrequent and the levels are not elevated. Therefore, adverse health effects are not expected from exposure to these chemicals.

Surface Water Pathway--East Soldier Creek

The majority of water in East Soldier Creek is released from the IWTP [900,000 gallons per day (gpd) flow generated by IWTP].5 Therefore, ATSDR assumes that water quality in East Soldier Creek downstream from the IWTP is similar to effluent from the plant. Unlike the evaluation of sediment, surface water in East Soldier Creek is not evaluated specific to the location since the water will flow from the IWTP and downstream to all locations. Maximum concentrations detected in the Soldier Creek RI/FS (presented in Table 5) are used to evaluate exposure. The available health guidelines cited in Table 5 are drinking water standards and are based on intake rates greater than those expected for a nonpotable surface water source. These guidelines are very conservative when used as nonpotable water standards. Inhalation was not considered as a route of exposure for metals because metals are not expected to volatilize from the creeks. The concentrations detected in the RI/FS study are considered to be representative of surface water, except during times of NPDES noncompliance discharges. Exposure as a result of NPDES noncompliance discharges are discussed separately. The NPDES data is presented in Table 7.

Bromodichloromethane was detected in surface water at a maximum concentration of 6 ppb. Estimated exposure by incidental ingestion is 1000-fold less than the oral RfD for bromodichloromethane.55 Dermal and inhalation exposures at the reported concentrations would not be significant. Also, no increased cancer risk from exposure to bromodichloromethane is expected. Thus, neither cancerous or noncancerous adverse health effects are expected to result from exposure to this contaminant in East Soldier Creek surface water.

PCE was detected in surface water at a maximum concentration of 3 ppb. Estimated ingestion doses are tenfold below the oral RfD for PCE. Dermal and inhalation exposures at the reported concentrations would not be significant. Also, there is no increased cancer risk from exposure to PCE. Thus, both cancerous and noncancerous adverse health effects are not expected to result from exposure to this contaminant in East Soldier Creek surface waters.

There are three major species of chromium: chromium VI, chromium III, and chromium 0. Chromium VI is irritating and short-term high-level exposure may result in adverse health effects at the site of contact.99 Chromium III does not result in these effects and is thought to be an essential food nutrient when taken in small amounts, although large amounts may be harmful.99 Exposure to chromium 0 is less common and is not well characterized in terms of exposure levels or potential health effects.

Chromium was not speciated during analysis of East Soldier Creek surface water samples. Therefore, ATSDR used health guidelines for chromium VI, the more toxic species, to evaluate potential toxicity from exposure. ATSDR used the more conservative values because chromium VI is being used in industrial operations at Tinker. However, the typical ratio of chromium discharged from the IWTP is one part chromium VI to five parts chromium III.67 In addition, chromium VI can be reduced to chromium III by organic matter present in water.55 Therefore, it is unlikely that the chromium detected is 100% chromium VI.

Chromium was detected in the surface water at a maximum of 156 ppb. The estimated oral exposures are tenfold below the oral RfD for chromium VI. In addition, the estimated exposure is much less than the upper range of the estimated safe and adequate daily dietary intake of 0.2 mg/day.99 Thus, noncancerous adverse health effects are not expected to result from oral exposure to chromium in East Soldier Creek surface waters.

It is unlikely that exposures to chromium in the sediment of East Soldier Creek would increase the risk of cancer. The EPA classifies chromium VI as a known human carcinogen via inhalation based on occupational epidemiologic studies of chromium-exposed workers. Inhalation and intratracheal studies with chromium (VI) compounds in animals also support the carcinogenic findings in humans.99 However, exposure to chromium VI by inhalation was not identified as a route of exposure for this site. There are no long-term studies that suggest that cancer is associated with ingestion of chromium VI.55,99

Manganese was detected in East Soldier Creek surface waters at a maximum concentration of 493 ppb. The estimated oral exposure dose is tenfold less than the RfD for manganese. Very little manganese will enter your body through your skin, so dermal contact is not of concern.100 Therefore, noncancerous adverse health effects are not expected to result from contact with manganese in East Soldier Creek surface waters.

Existing studies, both human and animal, are inadequate to assess the carcinogenicity of manganese.55

Arsenic was reported at a maximum concentration of 6.4 ppb in surface water. The reported value is the detection limit for the analysis. Therefore, concentrations are equal to or less than the value reported. Using the maximum value as a conservative estimate, the estimated ingestion is tenfold less than the RfD for arsenic. Small amounts of arsenic may enter the body through the skin, but this is not usually an important consideration.101 Also, no increased cancer risk is expected to result from arsenic contaminated surface water based on calculations using the cancer slope factor for arsenic. Therefore, noncancerous and cancerous adverse health effects are not expected to result from oral exposure to arsenic in East Soldier Creek surface waters.

The IWTP has a NPDES permit to discharge treated industrial wastewater to East Soldier Creek. Approximately 900,000 gallons of treated effluent are generated per day; this discharge creates the majority of water flow in the creek.5 Therefore, ATSDR assumes the water quality downstream from the IWTP is similar to effluent from the plant.

The Clean Water Act controls the direct discharge of pollutants to surface waters through the NPDES program.102 NPDES requires permits for direct discharges to surface waters, such as East Soldier Creek. The permit contains limits based upon either effluent standards, or, if they are more stringent, ambient water quality standards. NPDES permit limits are set according to the best available technology economically achievable. The permit limits are often lower than drinking water standards. Therefore, in general, adverse health effects from exposures to the treated water discharged to East Soldier Creek are not expected. However, during permit violations, it would be possible for concentrations in the surface water to reach levels that are of public health concern. Therefore, ATSDR reviewed NPDES reports from September 1988 through January 1994. The maximum concentrations released during noncompliance discharges are reported in Table 7. ATSDR evaluated these NPDES discharges as possible short-term exposures to persons who come in contact with water in East Soldier Creek following a NPDES violation.

Chemicals released to the creek and reported at concentrations in violation of the NPDES permit included: copper, total chromium, chromium VI, cyanide, zinc, phenol, cadmium, lead, and phosphorus. The average monthly and maximum effluent concentrations from 1988 to 1994 for each of those chemicals are graphically presented in Appendix I. The graphs show the relationship of the NPDES permit limit, the health guideline, and the monthly effluent concentrations (average and maximum) for each chemical.

The maximum reported NPDES violation for copper (1.0 ppm) is less than the MCLG (1.3 ppm). The ten-day health advisory for total chromium and chromium VI (1.4 ppm) is similar to the maximum reported NPDES violation (1.8 ppm). The LTHA for cyanide (0.15 ppm) is 2-fold greater than the maximum permit violation (0.08 ppm). The MCLG, ten-day health advisory, and LTHA are drinking water guidelines. Incidental ingestion while playing or working near the creek would be much less than the intake rate for a drinking water source.

The maximum reported NPDES violations for zinc, phenol, and cadmium are 18 ppm, 12 ppm, and 0.03 ppm, respectively. Using a daily intake rate of 50 milliliters (mls), the estimated exposure to zinc (0.03 mg/kg/day) is 3-fold less than the RfD, the exposure to phenol (0.06 mg/kg/day) is 10-fold less than the RfD, and the exposure to cadmium (0.0002 mg/kg/day) is 2.5-fold less than the RfD.

An appropriate health standard is not available for evaluating the exposure to lead in surface water. The maximum NPDES violation was 1.0 ppm. Only two violations of the permit for lead occurred during the six years of reports that were reviewed. Adverse health effects are not expected from an acute exposure to these concentrations in surface water.

The maximum NPDES discharge of phosphorus was 9.30 ppm. The NPDES permit analysis of phosphorus includes both inorganic and organic phosphates.67 Phosphorus, in the form of phosphate, is common to most foods. The average daily intake of phosphorus in the United States is approximately 1,500 mg. The Recommended Dietary Allowance (RDA) is 800 mg for children aged 1 to 10 and adults 19 years or more. Children between 11 and 18 and pregnant and nursing women should consume 1,200 mg daily.103

Assuming a daily consumption of 50 mls water/day via incidental ingestion of surface water from East Soldier Creek, the estimated exposure is less than 1 mg/day of phosphorus. This exposure is significantly less than the RDA for both children and adults.

The health standards used in the evaluation above are highly conservative when used to evaluate surface water. In addition, the concentration reported during the NPDES violation does not represent daily concentrations in the surface water. Exposures to these elevated concentrations would be infrequent.

In summary, evaluation of the NPDES violations from 1988 to 1994 determined that concentrations of chemicals released to the creek were not of public health concern. People may have been exposed to concentrations of contaminants similar to the concentrations discharged during a NPDES excursion. Those exposures are expected to be of short-term duration and are not considered representative of chronic exposure. Exposures would occur by incidental ingestion of and dermal contact with the water.

Sediment Pathway--West Soldier Creek

Children may play in West Soldier Creek and could be exposed to contaminants in the sediments. ATSDR assumed that children come in contact with the creek (play/wade/swim) 90 days a year [five days a week during the summer (June-August) and once a week during the fall and spring] and ingest 100 mg of sediment and 50 ml of creek water each time they play. Of the sampling locations, W07, near a trailer park, is the one where children would most likely play. Based on the scenario above, children are not expected to have adverse health effects from exposure to West Soldier Creek sediment.

Workers may be exposed to contaminated sediments in West Soldier Creek. Sampling locations W03 and W04 are near outfalls of building 3001 where employees might be working. Upon evaluation of this pathway and the contaminants detected that have health comparison values (see Table 9), arsenic, beryllium, cadmium, chromium, manganese, and nickel do not pose a public health threat to workers. Polycyclic aromatic hydrocarbons, cobalt, and lead do not have health comparison values and are evaluated below.

Using the TEF approach to evaluate the carcinogenic PAHs, the adjusted total PAH concentration is 6.0 ppm. Daily exposure is not expected at this location and infrequent exposure is not a health concern.

Several PAHs, both carcinogenic and noncarcinogenic, were detected in West Soldier Creek sediment. Carcinogenic PAHs detected include: benz(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, and benzo(a)pyrene. Phenanthrene is the only noncarcinogenic PAH detected.

Benzo(b)fluoranthene and benzo(a)pyrene were detected in the sediments greater than daily exposure risk-based concentrations for residential soil.96 However, people are not expected to be exposed daily to sediments in West Soldier Creek. Therefore, because people would be exposed infrequently these contaminants do not pose a health concern.

Chronic dermatitis and hyperkeratosis have been seen in workers exposed chronically to substances that contain PAHs. However, those exposures have been at much greater concentrations than those at Tinker. Absorption of PAHs from dermal contact with soil is expected to be minimal. Studies using human skin reported only 3% permeation of an applied dose of benzo(a)pyrene after 24 hours.98 Thus, skin contact with PAH-contaminated sediment in West Soldier Creek is not expected to cause adverse noncancerous health effects.

Exposures of workers to cobalt in West Soldier Creek sediments are not expected to result in adverse health effects. Cobalt was detected at a maximum of 52.1 ppm in the sediment at sampling location W03 (next to Building 3001). The primary target organs for the effects of cobalt in humans are the respiratory system following inhalation and the cardiac and blood systems following oral exposure.104 Effects of cobalt ingestion (cobalt sulfate in beer or cobalt chloride as treatment for anemia) that have been observed in humans include cardiomyopathy, gastrointestinal effects, visual disturbances, and thyroid effects. However, these adverse effects have been observed following exposures to significantly higher (1000 fold) concentrations than those detected at Tinker.104 Cobalt has not been shown to cause cancer in humans by any exposure route.

Exposure to the maximum concentration of lead in sediments of West Soldier Creek is not of public health concern for workers or children. The maximum concentration of lead detected in sediment was 243 ppm at location W03.

Surface Water Pathway--West Soldier Creek

Children who play in and around West Soldier Creek could be exposed to contaminants in the surface water. Sampling location, W07, is near a trailer park where children are most likely to play in the stream. However, based on the concentrations detected no adverse health effects are expected to result from exposures to surface water at this location.

Workers may be exposed to contaminated surface water in West Soldier Creek. Upon evaluation of this pathway and the contaminant concentrations detected (see Table 8), there is no apparent risk to the health of workers.

Sediment Pathway--Crutcho and Kuhlman Creeks

There were several sampling locations for sediment along Crutcho and Kuhlman Creeks. ATSDR focused on sampling locations 6-15 for Crutcho Creek and location 1 for Kuhlman Creek since they are in or near on-base neighborhoods and there is the potential for human exposure, especially for children, in these areas. Evaluation of this pathway determined that the contaminants detected with health comparison values (see Table 10), barium, beryllium, chromium, manganese, 4,4-DDD, and Aroclor-1260, do not pose a public health threat to children or adults. Arsenic is a Class A carcinogen and was detected at high levels off base and lead does not have any comparison values. Thus they are evaluated below.

For the sampling locations along Crutcho Creek in the areas where children might be exposed, arsenic was detected at a maximum concentration of 6.4 ppm at sampling location SD15E. No adverse health effects are expected to result from exposures to arsenic at this concentration.

Arsenic was detected at a maximum concentration of 22.3 ppm at sampling location SDB1 which is upstream of the base. This concentration represents concentrations coming onto the base and cannot be attributed to Tinker. Also, children are not expected to be in the area where this sample was taken. Thus, the arsenic levels detected in Crutcho Creek sediment do not pose a public health threat.

Lead was detected at a concentration of 87 ppm at sampling location SD15E in the area where children might be exposed. However, exposure to sediment with these concentrations of lead is not of public health concern for children. The maximum concentration of lead detected was 309 ppm at location SD26. Daily exposure of children to sediment at location SD26 in the creek may be of slight concern. However, in general, children are not expected to be exposed to sediments in the creek on a daily basis. In addition, exposure of children at location SD26 is not expected to occur.

Air Pathway

Ambient air in the vicinity of the IWTP was identified as a completed pathway. In March 1994, ATSDR issued a Health Consultation based on the results of the 1993 air sampling program. The consultation is included in Appendix G.

In the consultation, ATSDR concluded that adverse health effects are not expected as a result of exposure to ambient air concentrations detected in the 1993 IWTP ambient air study. However, current emissions of hydrogen sulfide may result in odors that are perceived as a nuisance to the local community. Emissions in the past may have been greater than the concentrations detected in the 1993 IWTP study. However, based on the available data, past exposures cannot be adequately determined to evaluate those past exposures. ATSDR recommended that ambient air monitoring stations be established in the vicinity of the IWTP and that the Air Force continue to modify the IWTP to better control emissions from the facility.

Phenol was detected above the Oklahoma MAAC (Maximum Ambient Air Concentration) in the initial ambient air sampling at the IWTP. The source of the contamination is believed to be volatilization of VOCs from tanks D1/D2 and holding tanks at the IWTP.

The community is concerned about ambient air exposures in the past. In an effort to address past exposure, ATSDR reviewed available influent phenol concentrations (January 1992 through February 1994) to the D1/D2 holding tanks at the IWTP.105 Influent concentrations of phenol peak when stripping processes occur in Building 3001. The data show that the plant received similar peak concentrations of phenol over the two year period. One unusual influent peak occurred during May 1993. The concentrations were about 2-fold greater than other peaks during the two year period. Ambient air concentrations of phenol were detected above the Oklahoma MAAC during this month (the initial ambient air sampling). The ambient air samples collected during the air sampling program (discussed in the consultation) were taken during a month when the influent concentrations were similar to other months in 1992 and 1993. Therefore, the data should be representative of exposures over this time period. Data is not available to address potential exposure prior to 1992.

Health Outcome Data Evaluation

The health outcome data available was reviewed by ATSDR and was determined as insufficient for evaluation. The available statistics are reported at the county level and are not specific for the exposed population.

Mortality Statistics

Mortality and death certificate data is available for Oklahoma County through the Center for Disease Control and Prevention's WONDER (Wide-ranging ONline Data for Epidemiologic Research) database. WONDER is a computerized information system that provides on-line access to epidemiologic and public health data sets. Those data are not site-specific, they are reported at the county level. Because the information is not community specific, it does not provide the data necessary to adequately draw conclusions concerning health issues as they relate to the site.

Riggin's Mortality Tapes

Riggin's Mortality Tapes provide information on deaths by county, state, and the U.S.; it does not provide site-specific information. Because the information is not specific for the community of concern, it does not provide the data necessary to adequately draw conclusions concerning health issues as they relate to the community.

Tumor Registry

Oklahoma is currently designing a tumor registry. Once the registry begins collecting information, several years of data collection will be necessary before the registry may be used for determining if and where high cancer rates exist.

Community Health Concerns Evaluation

Following are health concerns the community has raised and ATSDR's response:

1. How extensive and harmful is the contamination of the Garber-Wellington aquifer? What about future water use?
    Contamination of the Garber-Wellington Aquifer has occurred on the installation. However, most of the contamination is confined to the shallow groundwater (< 150 feet) on the installation. The private wells in communities immediately northeast of Tinker are also contaminated. The extent and severity of the contamination, as well as all its potential sources (which may include off-base sources of contamination as well as on-base sources), have not been fully characterized.

    To ensure no future impact on drinking water sources, Tinker has installed a series of monitoring wells. Tinker has 66 monitoring wells in the northeast quadrant of the base that are sampled on an annual basis. These wells have been sampled annually since 1992. Twelve well clusters (36 wells) have been installed under the existing off-base investigation. These new wells are in the vicinity of off-base private wells. Samples from these additional wells will be representative of groundwater contamination in the area. Sampling of these wells began in early 1995.

    ATSDR recommends that people not use private well water in the Kimsey Addition or the area near the intersection of Douglas Boulevard and S.E. 29th Street (areas 1 and 2 on Figure 4b).

2. How safe are the drinking water supplies?
    There are two sources of drinking water in the area. A surface water supply is available through the municipal water lines. This water is tested according to the EPA's Safe Drinking Water Act and is safe to drink. The water provided from the municipal source is safe for all purposes, including drinking and bathing.

    The other drinking water source is groundwater. Community (well serves several homes, i.e., trailer park well) and private wells are located in neighborhoods near Tinker. Some wells have been found to be contaminated while others are currently free of chemical contamination. However, the potential does exist for contaminants to migrate to those wells located downgradient from the several potential sources of contamination. Therefore, we recommend that the water from private and community wells in the Kimsey Addition, Evergreen Trailer Park, and neighborhoods near the intersection of 29th Street and Douglas Boulevard not be used for any purpose.

    Groundwater is also used by the base for drinking water (base supply wells). Contamination has been detected in two wells near Building 3001. These wells were immediately taken out of service. The wells that are currently in use are monitored according to the Safe Drinking Water Act.

3. Is the drinking water in Building 3001 and coffee made with it safe to consume?
    Yes. The water is tested according to the Safe Drinking Water Act to ensure the water meets regulatory standards prior to its distribution. No future exposures are expected through use of base water supplies.
4. Is our well water safe for laundry and showering -- it has black particles in it and is greasy?
    The majority of residences around Tinker AFB are now hooked to municipal water lines. The municipal water is safe to use for all purposes - drinking, showering, bathing, laundering.

    The black particles and the greasy film on the water may be a result of high mineral content of the water. The water in the Tinker area has a high mineral content and is considered hard water. Hard water often forms scaly deposits on the inner surfaces of cooking utensils and pipes that carry hot water. Mineral salts in hard water can precipitate the fatty acids from soap (i.e., laundry detergents and bath soap) in the form of a scum or jelly-like particles.106

5. Could washing a convenience store parking lot with well water cause rashes and sores on legs?
    After reviewing available data for wells in the area, ATSDR concluded that skin rashes and sores would not be expected from exposure to the contaminated well water.

    The rashes and sores may be a result of exposure to spilled gasoline. Appropriate protective clothing and knee length boots should be worn while washing down parking lots to protect workers from splashed gasoline.

6. Could past exposures to contaminated groundwater cause heart defects or chronic diarrhea in my daughter?
    Based on the information reviewed by ATSDR, it is not likely that diarrhea or heart defects could result from past exposures to contaminated groundwater.

    Short-term exposures to trichloroethylene (TCE) and 1,2-DCA at high concentrations have been associated with irregular heartbeats (cardiac arrhythmias). For example, the use of TCE as an anesthetic (i.e., concentrated TCE) has been linked with cardiac arrhythmias. However, based on the data provided to ATSDR, the concentrations of VOCs detected in the wells around Tinker are much lower and exposure is not expected to cause cardiac arrhythmias.

    Although fetuses in the first three months of pregnancy may be especially sensitive to TCE, the concentrations of TCE detected at Tinker (5.2-13.8 ppb) are much less than the concentrations associated with birth defects. Epidemiologic studies have found an association between pregnant women's chronic exposure to TCE-contaminated drinking water and congenital heart defects in their children.83 However, these studies were concerned with exposures of 6-239 ppb; thus, the upper limit of exposure in these studies is much higher than the exposure at Tinker. Further, the significance of this finding is questionable because of the possibility that the women were exposed to multiple chemicals, so it is not possible to be sure that the birth defects were not caused by one of the other chemicals or by all the chemicals together.

    Although 1,2-dichloroethane, TCE, and antimony can cause diarrhea, they are not expected to cause it at the concentrations detected in private wells. Thus, based on the information reviewed by ATSDR, it is not likely that diarrhea or heart defects could result from past exposures to contaminated groundwater.

7. I live near the base. Is my fetus safe from groundwater contamination?
    TCE and PCE were detected in contaminated groundwater from private wells. However, TCE and PCE were not detected in private wells at concentrations sufficient to produce developmental problems.
8. Is there an unusually high cancer rate in the communities surrounding Tinker?
    We do not know if the communities around Tinker have an unusually high cancer rate. There is no available data on cancer rates that is applicable at the community level.

    Evaluation of data in this public health assessment determined that an increase in cancer risk is unlikely from exposures to current ambient air emissions from the IWTP or from exposures to contaminated private well water.

9. Could lupus be related to base contamination?
    None of the chemicals that are associated with a lupus-like syndrome in susceptible individuals are present at levels of concern near Tinker AFB.

    Systemic lupus erythematosus is a chronic multisystem inflammatory disorder. In lupus, the immune system forms antibodies to the body's own tissue and attacks the organs and body systems. The exact cause of lupus is unknown. However, certain drugs and chemicals can induce a lupus-like syndrome.107 The chemicals associated with lupus can be divided into four classes: aromatic amines, hydrazines, sulfur containing drugs, and the hydralazine anti-convulsants.

10. How can the volatilization of jet fuel from fuel spills affect our health?
    Tinker has established procedures to prevent injury or exposure from jet fuel spills. These procedures are included in Tinker AFB Spill Prevention and Emergency Response Plan. These procedures are designed to contain spills and prevent exposures. Because the base has immediate response procedures, the bulk of a spill would be contained within the near vicinity of the actual incident. However, some chemicals would volatilize from a spill and be released to the air. The concentrations would be greatest in the immediate area of the incident. The wind would disperse the chemicals and the concentrations would be lower with increasing distance from a spill. Therefore, only people near a spill area are expected to be exposed to elevated concentrations in the air. The emergency procedures for spill containment include evacuation of people if determined necessary. In addition, this type of exposure is an acute or shortterm exposure. Therefore, ATSDR does not expect the exposures to be of health concern for the communities adjacent to Tinker AFB.

    Jet fuels are composed of a complex mixture of hydrocarbons (benzene, toluene, xylenes, and PAHs). Because jet fuel is a mixture of several components, limited toxicity information is available on their combined health effects.

    The association between jet fuel and cancer was evaluated by the International Agency for Research on Cancer Working Group on the Evaluation of Carcinogenic Risks to Humans. The Working Group concluded that there is insufficient evidence to determine that jet fuel causes cancer in animals or humans.108

11. Can children wading in Soldier Creek develop chloracne?
    ATSDR considers this unlikely. The concentrations and types of contaminants that have been reported in Soldier Creek have not been associated with chloracne.

    The Oklahoma City/County Health Department maintains a log of complaints by residents. Complaints about children developing skin irritations/rashes after wading in Soldier Creek are included in the log. Citizens can report complaints and have them included in the log by calling the Oklahoma City/County Health Department.

12. Is it unsafe for children to play in or around Soldier Creek due to the environmental contamination?
    ATSDR recommends that children not use the creek as a frequent play area. We do not expect health effects from limited contact with the water or sediments of the creek. However, to be cautious, children should avoid playing in the creek on a regular basis. Tinker is permitted to discharge treated wastewater into the creek and a possibility of an acute exposure exist if the children are in the creek during discharge of a significantly concentrated effluent. These acute exposures are very unlikely. Tinker has a spill control structure immediately downstream of the IWTP that is closed as soon as a release is suspected.
13. Two children developed skin irritations after playing in East Soldier Creek downstream of the IWTP last August (1993). Could chemicals from Tinker have caused their skin irritations?
    We do not think these skin rashes were caused by contamination in the creek.

    The IWTP is required to report any discharge above its NPDES permit limit. We reviewed all these reports from September 1988 through January 1994. No violations were determined to be of public health concern.

    Three violations of water quality standards occurred during August 1993: 1) on 1 August 93 the chemical oxygen demand was 1248 lbs/day versus the permit limit of 1126 lbs/day; 2) on 3 August 93 biochemical oxygen demand was 24 mg/L versus the permit limit of 15 mg/L; and 3) on 24 August 93 the total suspended solids was 56 mg/L versus the permit limit of 50 mg/L. Skin irritations (rashes) would not be expected from exposure to the water in East Soldier following these types of violations.

14. When wastewater from the base overflows into Crutcho and Soldier Creeks, can contaminants that are harmful enter these water systems?
    No wastewater from a treatment plant is discharged into Crutcho Creek. During rainstorms, surface runoff is collected and discharged into Crutcho Creek. But no adverse health effects are expected from exposure to contaminants detected in the surface water of the creek.

    Treated sanitary and industrial wastewaters are discharged into East Soldier Creek. Occasionally, during periods of heavy rainfall the final clarifiers of the wastewater treatment plant will overflow. This would result in the effluent being higher in suspended solids than desired. However, the overflow is further treated by going through a final filtration stage. Data are not available on the quality of the treated water during one of these rain events.

15. Are the fish caught in Soldier Creek safe to eat?
    Based on the data reviewed by ATSDR, we think the fish caught in Soldier Creek are safe to eat.

    One environmental concern is that metals can bioconcentrate in fish tissue. The metals cadmium, beryllium, antimony, chromium, and manganese were detected in Soldier Creek sediments at levels above soil comparison values. The metals chromium, manganese, cadmium, and arsenic were detected in Soldier Creek surface waters at levels above drinking water comparison values. However, the concentrations were relatively low and were not a health concern for people who have come into contact with creek water or sediments. Although these metals can bioconcentrate in fish, it is unlikely that at the concentrations detected in the creek they would pose a health concern for fish consumption.

16. Is it possible that contaminants have entered yards adjacent to Soldier Creek and would garden vegetables from those yards be harmful if consumed?
    Flooding has occurred along Soldier Creek from Reno Street to 23rd Street. This flooding occurs during heavy rain events. However, flooding is infrequent, occurring about once every five years. Therefore, the possibility of contaminant migration from Soldier Creek into adjacent yards is unlikely.

    It is possible that contaminants could bioaccumulate if contaminated water from the creek is used to water yards and gardens. However, levels of contamination detected in Soldier Creek surface water are not expected to result in contaminant concentrations in vegetables that would be of public health concern.

17. Our garden vegetables and plants have black, oily particles on them? What could it be and is it safe?
    Environmental sampling of the fruits and vegetables is necessary to fully answer this question. ATSDR has no information to determine what is on the garden crops. And, without information about what is on the fruits and vegetables ATSDR cannot determine if it is safe to eat the crops.

    ATSDR recommends that the fruits and vegetables be thoroughly washed and peeled, if possible, to remove the substance before preparing the food.

18. Is the air safe in the vicinity of the IWTP?
    ATSDR issued a health consultation in March 1994 that evaluated air emissions from the IWTP. ATSDR concluded that current emissions from the IWTP were not a health concern for children or adults in the nearby residential area or for workers at the IWTP. The health consultation is attached in Appendix G.

    ATSDR concluded that emissions of hydrogen sulfide were at concentrations that may be perceived as a nuisance to the community. ATSDR recommended that the Air Force develop an on-going air monitoring program at the IWTP. The Air Force has developed such a program and has begun implementation of the program.

19. I live adjacent to the base and experience sinus problems and a tight chest periodically. Could this be caused by air pollution and contaminated water from the IWTP?
    These health effects should not occur as a result of exposure to water discharged from the IWTP.

    People could be exposed to contaminants that evaporate from the wastewater while it is held in tanks at the IWTP prior to treatment. However, ATSDR issued a health consultation in March 1994 that concluded that current emissions from the IWTP were not a health concern for children or adults in the nearby residential area or for workers at the IWTP.

20. I live adjacent to the base and have experienced dermal reactions such as dry and itchy scalp, rashes, open sores, and skin growths. Could this be caused by air pollution and contaminated water from the IWTP?
    ATSDR does not expect exposures to air emissions from the IWTP to result in the array of skin disorders described.

    Phenols were detected in the air in the vicinity of the IWTP during the initial investigations of ambient air at the IWTP. Although the association between skin irritation (dermatitis) and exposure to airborne phenol has not been established, it is suspected that dermatitis is associated with exposure to phenol.109

    Phenol was detected at 140 ppb in May of 1993, a concentration above the Oklahoma Maximum Ambient Air Concentration of 100 ppb. After the base reviewed their records, it determined that the peak occurred during a time of unusually high use of phenol in an industrial process at Tinker. The Air Force is monitoring the use of phenol to avoid these short-term peaks. ATSDR's review of the phenol influent to the IWTP from January 1993 through February 1994 showed that May 1993 was the only period when the phenol was unusually elevated during normal industrial activity.

    Treated wastewater from the IWTP is discharged to East Soldier Creek. During the remedial investigation, no contamination was detected in the surface water or sediments of the creek that was of public health concern.

21. Will children enrolled at the Childhood Development Center be safe from contamination?
    Yes, the children will be safe. ATSDR issued a health consultation in March 1994 that concluded that current emissions from the IWTP were not a health concern for children at the Child Development Center. A report issued by the Center for Disease Control and Prevention during the site selection process concluded that exposures to the soils around the Child Development Center were not a health concern.110 The drinking water for the Child Development Center is a mixture of municipal and base water. These water systems are in compliance with the Safe Drinking Water Act.
22. Is it safe for employees to work near the hazardous waste sites?
    Building 3001 is the area of most concern since it houses about 8,000 workers under one roof. Since contaminants are located under the building, direct contact with them is unlikely. Currently, the drinking water workers use is safe because protective measures have been taken by the base. On-base wells that were contaminated are no longer used for drinking water.

    Current air emissions at the IWTP were determined as no apparent health hazard for workers. On May 31, 1995, air samples were collected at the Chemical Cleaning Subunit in Building 3001.111 The samples were analyzed for TCE. TCE was not detected above the detection limit of 0.28 mg/m3. The TLV is 269 mg/m3.

    ATSDR is only authorized to address worker safety as it relates to the hazardous waste sites on base. Worker safety concerns about normal operations should be referred to the Occupational Safety and Health Administration who regulates worker safety for current work procedures.

23. Is it safe to hunt? Is the wildlife safe to consume?
    Hunting is not allowed on base. Areas where hunting is allowed are far away from the base and from areas of known contamination. Contamination from Tinker is not expected to impact hunting areas.

    There is no evidence that the on-base fishing pond is contaminated.



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