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Focused

Public Health Assessment

Drinking Water Supplies and Groundwater Pathway Evaluation

Isla de Vieques Bombing Range
Vieques, Puerto Rico


APPENDICES

APPENDIX A: GLOSSARY

ATSDR Plain Language Glossary of Environmental Health Terms

Adverse Health Effect:
A change in body function or the structures of cells that can lead to disease or health problems.


ATSDR:
The Agency for Toxic Substances and Disease Registry. ATSDR is a federal health agency in Atlanta, Georgia that deals with hazardous substance and waste site issues. ATSDR gives people information about harmful chemicals in their environment and tells people how to protect themselves from coming into contact with chemicals.


Biota:
Used in public health, things that humans would eat - including animals, fish and plants.


Cancer:
A group of diseases which occur when cells in the body become abnormal and grow, or multiply, out of control


Carcinogen:
Any substance shown to cause tumors or cancer in experimental studies.


Chronic Exposure:
A contact with a substance or chemical that happens over a long period of time. ATSDR considers exposures of more than one year to be chronic.


Completed Exposure Pathway:
See Exposure Pathway.


Comparison Value (CVs):
Concentrations or the amount of substances in air, water, food, and soil that are unlikely, upon exposure, to cause adverse health effects. Comparison values are used by health assessors to select which substances and environmental media (air, water, food and soil) need additional evaluation while health concerns or effects are investigated.


Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA):
CERCLA was put into place in 1980. It is also known as Superfund. This act concerns releases of hazardous substances into the environment, and the cleanup of these substances and hazardous waste sites. ATSDR was created by this act and is responsible for looking into the health issues related to hazardous waste sites.


Concern:
A belief or worry that chemicals in the environment might cause harm to people.


Concentration:
How much or the amount of a substance present in a certain amount of soil, water, air, or food.


Contaminant:
See Environmental Contaminant.


Dermal Contact:
A chemical getting onto your skin. (see Route of Exposure).


Dose:
The amount of a substance to which a person may be exposed, usually on a daily basis. Dose is often explained as "amount of substance(s) per body weight per day".


Dose / Response:
The relationship between the amount of exposure (dose) and the change in body function or health that result.


Duration:
The amount of time (days, months, years) that a person is exposed to a chemical.


Environmental Contaminant:
A substance (chemical) that gets into a system (person, animal, or the environment) in amounts higher than that found in Background Level, or what would be expected.


Environmental Media:
Usually refers to the air, water, and soil in which chemicals of interest are found. Sometimes refers to the plants and animals that are eaten by humans. Environmental Media is the second part of an Exposure Pathway.


U.S. Environmental Protection Agency (EPA):
The federal agency that develops and enforces environmental laws to protect the environment and the public's health.


Epidemiology:
The study of the different factors that determine how often, in how many people, and in which people will disease occur.


Exposure:
Coming into contact with a chemical substance. (For the three ways people can come in contact with substances, see Route of Exposure.)


Exposure Assessment:
The process of finding the ways people come in contact with chemicals, how often and how long they come in contact with chemicals, and the amounts of chemicals with which they come in contact.


Exposure Pathway:
A description of the way that a chemical moves from its source (where it began) to where and how people can come into contact with (or get exposed to) the chemical.

ATSDR defines an exposure pathway as having 5 parts:

  1. Source of Contamination,
  2. Environmental Media and Transport Mechanism,
  3. Point of Exposure,
  4. Route of Exposure, and
  5. Receptor Population.


When all 5 parts of an exposure pathway are present, it is called a Completed Exposure Pathway. Each of these 5 terms is defined in this Glossary.


Frequency:
How often a person is exposed to a chemical over time; for example, every day, once a week, twice a month.


Hazardous Waste:
Substances that have been released or thrown away into the environment and, under certain conditions, could be harmful to people who come into contact with them.


Health Effect:
ATSDR deals only with Adverse Health Effects (see definition in this Glossary).


Indeterminate Public Health Hazard:
The category is used in Public Health Assessment documents for sites where important information is lacking (missing or has not yet been gathered) about site-related chemical exposures.


Ingestion:
Swallowing something, as in eating or drinking. It is a way a chemical can enter your body (See Route of Exposure).


Inhalation:
Breathing. It is a way a chemical can enter your body (See Route of Exposure).


Inorganic:
Compounds that do not contain hydrocarbon groups.


Isthmus:
A narrow passage connecting two larger cavities.


LOAEL:
Lowest Observed Adverse Effect Level. The lowest dose of a chemical in a study, or group of studies, that has caused harmful health effects in people or animals.


MCL:
Maximum Contaminant Level. The standard set by EPA for drinking water within public water supply systems. EPA considers the protection of human health when setting the MCL.


MRL:
Minimal Risk Level. An estimate of daily human exposure - by a specified route and length of time -- to a dose of chemical that is likely to be without a measurable risk of adverse, noncancerous effects. An MRL should not be used as a predictor of adverse health effects.


NPL:
The National Priorities List. (Which is part of Superfund.) A list kept by the U.S. Environmental Protection Agency (EPA) of the most serious, uncontrolled or abandoned hazardous waste sites in the country. An NPL site needs to be cleaned up or is being looked at to see if people can be exposed to chemicals from the site.


NOAEL:
No Observed Adverse Effect Level. The highest dose of a chemical in a study, or group of studies, that did not cause harmful health effects in people or animals.


No Apparent Public Health Hazard:
The category is used in ATSDR's Public Health Assessment documents for sites where exposure to site-related chemicals may have occurred in the past or is still occurring but the exposures are not at levels expected to cause adverse health effects.


No Public Health Hazard:
The category is used in ATSDR's Public Health Assessment documents for sites where there is evidence of an absence of exposure to site-related chemicals.


Ordnance:
Military materiels such as weapons, ammunition, combat vehicles, and equipment.


Organic:
Compounds containing carbon.


PHA:
Public Health Assessment. A report or document that looks at chemicals at a hazardous waste site and tells if people could be harmed from coming into contact with those chemicals. The PHA also tells if possible further public health actions are needed.


Point of Exposure:
The place where someone can come into contact with a contaminated environmental medium (air, water, food or soil). For examples:
the area of a playground that has contaminated dirt, a contaminated spring used for drinking water, the location where fruits or vegetables are grown in contaminated soil, or the backyard area where someone might breathe contaminated air.


Population:
A group of people living in a certain area; or the number of people in a certain area.


Public Health Hazard:
The category is used in PHAs for sites that have certain physical features or evidence of chronic, site-related chemical exposure that could result in adverse health effects.


Public Health Hazard Criteria:
PHA categories given to a site which tell whether people could be harmed by conditions present at the site. Each are defined in the Glossary. The categories are:

  1. Urgent Public Health Hazard
  2. Public Health Hazard
  3. Indeterminate Public Health Hazard
  4. No Apparent Public Health Hazard
  5. No Public Health Hazard

Receptor Population:
People who live or work in the path of one or more chemicals, and who could come into contact with them (See Exposure Pathway).


Reference Dose (RfD):
An estimate, with safety factors (see safety factor) built in, of the daily, life-time exposure of human populations to a possible hazard that is not likely to cause harm to the person.


Route of Exposure:
The way a chemical can get into a person's body. There are three exposure routes:

- breathing (also called inhalation),
- eating or drinking (also called ingestion), and
- or getting something on the skin (also called dermal contact).


Safety Factor:
Also called Uncertainty Factor. When scientists don't have enough information to decide if an exposure will cause harm to people, they use "safety factors" and formulas in place of the information that is not known. These factors and formulas can help determine the amount of a chemical that is not likely to cause harm to people.


Semi-volatile organic compound (SVOC):
A class of organic (carbon-containing) chemicals similar to VOCs, but that evaporate, or volatilize, less readily.


SMCL:
The Secondary Maximum Contaminant Level is established based on secondary considerations such as taste, odor, and appearance, when health concerns are not an issue.


Source (of Contamination):
The place where a chemical comes from, such as a landfill, pond, creek, incinerator, tank, or drum. Contaminant source is the first part of an Exposure Pathway.


Special Populations:
People who may be more sensitive to chemical exposures because of certain factors such as age, a disease they already have, occupation, sex, or certain behaviors (like cigarette smoking). Children, pregnant women, and older people are often considered special populations.


Toxic:
Harmful. Any substance or chemical can be toxic at a certain dose (amount). The dose is what determines the potential harm of a chemical and whether it would cause someone to get sick.


Toxicology:
The study of the harmful effects of chemicals on humans or animals.


Tumor:
Abnormal growth of tissue or cells that have formed a lump or mass.


Urgent Public Health Hazard:
This category is used in ATSDR's Public Health Assessment documents for sites that have certain physical features or evidence of short-term (less than 1 year), site-related chemical exposure that could result in adverse health effects and require quick intervention to stop people from being exposed.


Volatile Organic Compound (VOC):
A class of organic (carbon-containing) chemicals which readily evaporate, or volatilize. VOCs are frequently used as solvents, degreasing agents, and in other industrial applications.

APPENDIX B: SAMPLING SUMMARIES

Table B-1. Sampling Summary of the Public Water Supply System on Isla de Vieques, Puerto Rico

Name Location Use Sampling
Agency
Chemicals Sampled Date Sampled
VOCs/
SVOCs
Inorganics/
Metals
Pesticides/
Herbicides
PCBs Explosives
Arcadia Tank Naval Ammunitions Support Detachment (NASD) Public water supply tank owned by Puerto Rico Aqueduct and Sewer Authority (PRASA) Puerto Rico Department of Health (DOH)         checkmark June 1999a
United States Environmental Protection Agency (USEPA) checkmark     September 1999
January 2000b
NASD Tank NASD Navy water supply tank (water is supplied from the mainland) USEPA     September 1999
January 2000b
The Navy's contractor     September 1999
Pilon Tank Pilon Public water supply tank owned by PRASA USEPA     September 1999
January 2000b
Esperanza Tank Esperanza Public water supply tank owned by PRASA Puerto Rico DOH         June 1999a
USEPA     September 1999
January 2000b
Florida Tanks (2) Florida Public water supply tank owned by PRASA Puerto Rico DOH         June 1999a
USEPA     September 1999
January 2000b
Martineau Tank Martineau Public water supply tank owned by PRASA USEPA     September 1999
January 2000b
Destino Tank Destino Public water supply tank owned by PRASA USEPA     September 1999
January 2000b
Leguillow Tank West of Isabel Segunda Public water supply tank owned by PRASA USEPA     September 1999
January 2000b
Los Chivos Tank Los Chivos Public water supply tank owned by PRASA USEPA     September 1999
January 2000b
Distribution Tank Unknown Public water supply tank owned by PRASA Puerto Rico DOH         June 1999a
Agencia Comercial Baldorioty Street Tap connected to the public water supply Puerto Rico DOH June 1999
Rio Blanco Input & Output Naguabo, Puerto Rico Filtration plant for public water supply USEPA         checkmark January 2000

aPR DOH also sampled for nitrate and nitrite.
bUSEPA only sampled for explosives.


Table B-2. Sampling Summary of Groundwater Wells on Isla de Vieques, Puerto Rico

Name Location Use Sampling Agency Chemicals Sampled  Date Sampled
VOCs/
SVOCs
Inorganics/
Metals
Pesticides/
Herbicides
PCBs Explosives
Well 2-3 Martineau Remote well used by the public when water supply is interrupted United States Environmental Protection Agency (USEPA) checkmark checkmark     checkmark September 1999
January 2000a
Well 3-7 Proyecto Barracon Local well used by the public when the water supply is interrupted USEPA checkmark checkmark     checkmark September 1999
January 2000a
Sun Bay Wells (3) Sun Bay Emergency water supply wells owned by Puerto Rico Aqueduct and Sewer Authority (PRASA) Puerto Rico Department of Health (DOH)  checkmark checkmark   checkmark checkmark    May 1995
USEPA checkmark  checkmark        September 1999
B Wells (4) Sun Bay Prior to their abandonment in 1978, these wells were part of the Esperanza valley well field Puerto Rico DOH  checkmark checkmark   checkmark checkmark    May 1995
Navy Well 14 Camp Garcia Former drinking water well The Navy's contractor checkmark  checkmark  checkmark checkmark   checkmark August 1999
Navy Wells (5) NASD Uncertain: one was a supply well (Navy Well 17) The Navy's contractor  checkmark  checkmark checkmark  checkmark  checkmark  August 1999
U.S. Geological Survey checkmark   checkmark checkmark      November 1996
Monitoring Wells (11) Along the Eastern Maneuver Area (EMA) western boundary Monitoring The Navy's contractor          checkmark August 1999

APPENDIX C: SAMPLED CHEMICALS

Volatile Organic Compounds EPA 1999b Baker 1999 PR DOH 1999 PR DOH 1995
1,1,1,2-Tetrachloroethane checkmark checkmark checkmark checkmark
1,1,1-Trichloroethane checkmark checkmark checkmark checkmark
1,1,2,2-Tetrachloroethane checkmark checkmark checkmark checkmark
1,1,2-Trichloroethane checkmark checkmark checkmark checkmark
1,1-Dichloroethane checkmark checkmark checkmark checkmark
1,1-Dichloroethylene checkmark checkmark checkmark   
1,1-Dichloropropene checkmark checkmark checkmark  
1,2,3-Trichlorobenzene checkmark checkmark checkmark checkmark
1,2,3-Trichloropropane checkmark checkmark checkmark checkmark
1,2,4-Trichlorobenzene checkmark checkmark checkmark checkmark
1,2,4-Trimethylbenzene checkmark checkmark checkmark checkmark
1,2-Dibromo-3-chloropropane checkmark checkmark checkmark checkmark
1,2-Dibromoethane checkmark checkmark checkmark checkmark
1,2-Dichloroethane checkmark checkmark checkmark checkmark
1,2-Dichloropropane checkmark checkmark checkmark  
1,3,5-Trimethylbenzene checkmark checkmark checkmark checkmark
1,3-Dichlorobenzene checkmark checkmark checkmark  
1,3-Dichloropropane checkmark checkmark checkmark  
1,2-Dibromo-3-chloropropane   checkmark    
1,4-Dibromo-3-chloropropane   checkmark    
2,2-Dichloropropane checkmark checkmark checkmark  
2-Butanone checkmark checkmark    
o-Chlorotoluene checkmark checkmark checkmark checkmark
2-Hexanone checkmark checkmark    
3-Chloropropene (Allylchloride)   checkmark    
p-Chlorotoluene checkmark checkmark checkmark checkmark
4-Methyl-2-pentanone checkmark checkmark    
Acenonitrile   checkmark    
Acetone checkmark checkmark    
Acrolein (Propenal)   checkmark    
Acrylonitrile checkmark checkmark    
Benzene checkmark checkmark checkmark checkmark
Bromobenzene checkmark checkmark checkmark checkmark
Bromochloromethane checkmark checkmark checkmark checkmark
Dichlorobromomethane checkmark checkmark checkmark checkmark
Bromoform checkmark checkmark checkmark checkmark
Bromomethane (Methyl bromide) checkmark checkmark checkmark checkmark
Butylbenzene checkmark   checkmark checkmark
Carbon disulfide checkmark checkmark    
Carbon tetrachloride checkmark checkmark checkmark checkmark
Chlorobenzene checkmark checkmark checkmark checkmark
Chloroethane checkmark checkmark checkmark checkmark
Chloroform checkmark checkmark checkmark checkmark
Chloromethane (Methyl chloride) checkmark checkmark checkmark checkmark
Chloroprene   checkmark checkmark  
cis 1,2-Dichloroethylene checkmark checkmark checkmark  
cis 1,3-Dichloropropene checkmark checkmark checkmark checkmark
Chlorodibromomethane checkmark checkmark checkmark checkmark
Dibromochloropropane       checkmark
Dibromomethane (Methylene bromide) checkmark checkmark checkmark checkmark
Dichlorodifluoromethane   checkmark checkmark checkmark
Ethyl methacrylate   checkmark    
Ethylbenzene checkmark checkmark checkmark checkmark
Hexachlorobutadiene checkmark checkmark checkmark checkmark
Iodomethane (Methyl iodide)   checkmark    
Isobutanol (Isobutyl alcohol)   checkmark    
Isopropylbenzene checkmark checkmark checkmark checkmark
m&p-Xylenes
  checkmark   checkmark
p-Xylenes       checkmark
Methacrylonitrile
  checkmark    
Methyl methacrylate   checkmark    
Methylene chloride (Dichloromethane) checkmark checkmark checkmark checkmark
Naphthalene checkmark checkmark   checkmark
n-Propylbenzene checkmark checkmark checkmark checkmark
o-Xylene   checkmark   checkmark
Pentachlorethane   checkmark    
P-Isopropyltoluene checkmark checkmark checkmark checkmark
Propionitrile   checkmark    
sec-Butylbenzene checkmark checkmark checkmark checkmark
Styrene checkmark checkmark checkmark checkmark
Tertbutylbenzene checkmark checkmark checkmark checkmark
Tetrachloroethylene checkmark checkmark checkmark checkmark
Toluene checkmark checkmark checkmark checkmark
trans 1,2-Dichloroethylene checkmark checkmark checkmark  
trans 1,3-Dichloropropene checkmark checkmark checkmark checkmark
trans-1,4-Dichloro-2-butene   checkmark    
Trichloroethylene checkmark checkmark checkmark checkmark
Trichlorofluoromethane checkmark checkmark checkmark checkmark
Vinyl acetate   checkmark    
Vinyl chloride checkmark checkmark checkmark checkmark
Xylenes (total) checkmark checkmark checkmark  
Total Trihalomethanes checkmark   checkmark  


Semi-volatile Organic Compounds EPA 1999b Baker 1999 PR DOH 1999 PR DOH 1995
1,2,4,5-Tetrachlorobenzene   checkmark    
1,2,4-Trichlorobenzene   checkmark    
1,2-Dichlorobenzene (o-Dichlorobenzene) checkmark checkmark checkmark checkmark
1,2-Diphenylhydrazine checkmark      
1,3,5-Trinitrobenzene   checkmark    
1,3-Dichlorobenzene (m-Dichlorobenzene) checkmark checkmark   checkmark
1,4-Dichlorobenzene (p-Dichlorobenzene) checkmark checkmark checkmark checkmark
1,4-Dioxane   checkmark    
1,4-Naphthoquinone   checkmark    
1,4-Phenylenediamene (p-Phenylenediamene)   checkmark    
1-Dillate   checkmark    
1-Naphthylamine   checkmark    
2,3,4,6-Tetrachlorophenol   checkmark    
2,4,5-Trichlorophenol checkmark checkmark    
2,4,6-Trichlorophenol checkmark checkmark    
2,4-Dichlorophenol checkmark checkmark    
2,4-Dimethylphenol checkmark checkmark    
2,4-Dinitrophenol checkmark checkmark    
2,4-Dinitrotoluene checkmark checkmark    
2,6-Dichlorophenol   checkmark    
2,6-Dinitrotoluene checkmark checkmark    
2-Acetylaminofluorene   checkmark    
2-Chloroethyl vinyl ether checkmark      
2-Chloronaphthalene checkmark checkmark    
2-Chlorophenol checkmark checkmark    
2-Diallate   checkmark    
2-Methyl naphthalene checkmark checkmark    
2-Naphthylamine   checkmark    
2-Nitroaniline (o-Nitroaniline) checkmark checkmark    
2-Nitrophenol (o-Nitrophenol) checkmark checkmark    
2-Picoline   checkmark    
3,3'-Dichlorobenzidine   checkmark    
3,3'-Dimethylbenzidine   checkmark    
3-Methylcholanthrene   checkmark    
3-Nitroaniline (m-Nitroaniline) checkmark checkmark    
4,6-Dinitro-2-methylphenol   checkmark    
4-Aminobiphenyl   checkmark    
4-Bromophenyl phenyl ether checkmark checkmark    
p-Chloro-m-cresol checkmark checkmark    
4-Chloroaniline (p-Chloroaniline) checkmark checkmark    
4-Chlorophenyl phenyl ether checkmark checkmark    
4-Nitroaniline (p-Nitroaniline) checkmark checkmark    
4-Nitroguinoline 1-oxide   checkmark    
4-Nitrophenol (p-Nitrophenol) checkmark checkmark    
5-Nitro-o-toluidine   checkmark    
7,12-Dimethylbenz(a)anthracene   checkmark    
Acenaphthene checkmark checkmark    
Acenaphthylene checkmark checkmark    
Acetophenone   checkmark    
alpha, alpha-Dimethylphenethylamine   checkmark    
Aniline   checkmark    
Anthracene checkmark checkmark    
Aramite (total)   checkmark    
Aramite-1   checkmark    
Aramite-2   checkmark    
1,2-Benzanthracene checkmark checkmark    
Benzo(a)pyrene checkmark checkmark checkmark checkmark
3,4-Benzofluoranthene (Benzo(b)fluoranthene) checkmark checkmark    
Benzoic acid checkmark      
1,12-Benzoperylene (Benzo(g,h,i)perylene) checkmark checkmark    
11,12-Benzofluoranthene (Benzo(k)fluoranthene) checkmark checkmark    
Benzyl alcohol checkmark checkmark    
Bis(2-chloroethoxy) methane checkmark checkmark    
Bis(2-chloroethyl) ether checkmark checkmark    
Bis(2-chloroisopropyl) ether checkmark      
Butyl benzyl phthalate checkmark checkmark    
Chrysene checkmark checkmark    
4-Methyl phenol (p-cresol) checkmark checkmark    
2-Methyl phenol (o-cresol) checkmark      
di(2-ethylhexyl)adipate     checkmark checkmark
Di(2-ethylhexyl)phthalate checkmark checkmark checkmark checkmark
Diethyl phthalate checkmark      
Diallate (total)   checkmark    
1,2:5,6-Dibenzanthracene (Dibenzo(a,h)anthracene) checkmark checkmark    
Dibenzofuran checkmark checkmark    
Dimethyl phthalate checkmark checkmark    
Di-n-butylphthalate checkmark checkmark    
Di-n-octylphthalate checkmark checkmark    
Dinoseb (2-sec-Butyl-4,6-dinitrophenol)   checkmark    
Ditrosol (4,6-Dinitro-o-cresol) checkmark      
Ethyl methanesulronate   checkmark    
Fluoranthene checkmark checkmark    
Fluorene checkmark checkmark    
Hexachlorobenzene checkmark checkmark checkmark checkmark
Hexachlorobutadiene checkmark checkmark    
Hexachlorocyclopentadiene checkmark checkmark checkmark checkmark
Hexachloroethane checkmark checkmark    
Hexachlorophene   checkmark    
Hexachloropropene   checkmark    
Ideno(1,2,3-c,d)pyrene checkmark checkmark    
Isophorone checkmark checkmark    
Isosafrole   checkmark    
m-Dinitrobenzene   checkmark