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Public Health Assessment

Air Pathway Evaluation

Isla de Vieques Bombing Range
Vieques, Puerto Rico


VI. COMMUNITY HEALTH CONCERNS

An integral part of the public health assessment process is addressing community concerns related to environmental health. Throughout this process, ATSDR has been working with, and will continue to work with, the Vieques community to define specific health issues of concern. On multiple trips to the island, ATSDR has met with numerous individuals and organizations, including local officials, physicians, nurses, pharmacists, leaders of women's groups, teachers, students, fishermen, businessmen, and families. Meeting with community members was critical to identifying and understanding residents' health concerns.

This PHA has addressed four key questions that community members have repeatedly asked about inhalation exposures to contaminants from the Navy's bombing range at Vieques. ATSDR's other PHAs have addressed, or will address, community concerns regarding levels of contamination in other environmental media, including water, soils, and food items. These documents address the main concerns that ATSDR has received since first working on the island of Vieques.

In addition to the four key questions pertaining to air contaminants released from the LIA (see Section V), ATSDR has identified other community concerns that are relevant to the air exposure pathway. These additional concerns are summarized below in three questions, along with ATSDR's responses.

A. Is Water from Rainfall Collection Systems Safe to Drink?

ATSDR Response: The majority of residents on Vieques receive drinking water from the public water supply, which draws from surface water (Rio Blanco) on the main island of Puerto Rico. However, ATSDR has received accounts that some residents obtain drinking water using rainfall collection systems. The exact number of residents with such systems is not known. The following paragraphs address the public health implications of obtain drinking water from these rainfall collection systems.

Rainwater can be a safe and reliable source of drinking water and is used widely for this purpose throughout the Caribbean. However, the method of collecting and treating rainwater determines how safe the water is. Because rooftops are open to the air, a wide range of materials might settle on them. These materials include leaves, mold spores, dead insects, bird droppings, and particulate matter from local sources of air pollution. Some of these materials can contain significant bacterial contamination. Though dusts from the LIA might blow in the air for several miles and then settle on the rooftops in the residential areas of Vieques, analyses in Section V suggest that local sources of air pollution (e.g., motor vehicles) probably account for a majority of particulate matter in these areas.

The following discussion first outlines recommended sanitation practices for obtaining drinking water from rainfall collection systems and then presents ATSDR's specific comments on use of these systems on Vieques.

General Sanitation Practices

When rainwater falls on rooftops, it can wash the various materials that have settled onto the rooftops into the device used to collect the rainwater, usually a cistern or a storage tank. If residents consume the untreated water that first flows from the rooftops, they might be exposed to a wide range of disease-causing bacteria. As evidence of harmful exposures, scientists have suspected that an outbreak of salmonella in the West Indies resulted from residents drinking water from a rooftop collection system that was heavily contaminated with bird feces (Koplan et al. 1978). Many other accounts of diseases caused by water-borne pathogens have been attributed to use of poorly maintained rainfall collection systems. Therefore, consumption of untreated water from rooftop collection systems is not advised.

Various health and environmental agencies have published guidelines for ensuring that rainfall collection systems provide for a safe drinking water supply. Many of these guidelines involve minimal monetary investments to implement. The following suggestions are provided in several references on good sanitation practices for obtaining drinking water (e.g., Salvato 1982, Texas Water Development Board 1997, United Nations Environment Programme 1997):

By following these and other sanitation practices, residents of Vieques can ensure that drinking water provided by rainfall collection systems is relatively free of contamination, including contaminants from local sources (e.g., birds, insects, motor vehicles), as well as the much smaller quantities of contaminants that might transport from the LIA.

Information Specific to Vieques

Focusing specifically on Vieques, ATSDR has learned that some community members obtain drinking water from rooftop collection systems (Cherry and Ramos 1995), though detailed information on the extent to which this takes place is not available. It is ATSDR's understanding that most residents converted their collection systems into closed tanks that now store water provided by the public water supply, and not by local rainwater. However, some residents may still use rainwater from rainfall collection systems in addition to water from the public water supply. The main community concern about the rainfall collection systems is that dusts from the LIA might settle on rooftops and eventually contaminate the rainwater that is collected.

No sampling studies have been conducted to characterize the quality of water in rainfall collection systems on Vieques. Therefore, no firm conclusions can be drawn based on site-specific sampling data. ATSDR's response to this question addresses the general advantages and disadvantages of using rainfall as a source of drinking water. If good sanitation practices are followed, rainfall collection systems on Vieques are expected to provide clean water that does not pose health hazards.

ATSDR has collected many documents that list recommended sanitation practices for rainfall collection systems. Some of these documents address issues specific to water supplies in the Caribbean. For the residents' benefit, ATSDR has placed copies of two key documents in the records repositories for the Vieques site, which are located at Biblioteca Publica on Vieques, the Vieques Conservation and Historical Trust, and at the University of Puerto Rico School of Public Health.

B. Is Exposure to the Material in African Dust Unhealthy?

ATSDR's Response: The purpose of this PHA is to evaluate the public health implications of exposures to air contamination associated with the Navy's military training activities on Vieques. When evaluating this issue, however, some Vieques residents also expressed concern that "African dust storms" might influence air quality on the island. To be responsive to these concerns, ATSDR researched the potential impacts of these dust storms and reached the conclusions summarized below.

Public Health Implications of African Dust Storms

As Section III.E explains, many researchers have studied African dust storms, or events in which strong winds blow large amounts of dust from arid northern Africa soils into the air. Some dust clouds have been observed thousands of miles from Africa, including over areas in the Caribbean and the southeastern United States. ATSDR emphasizes that the presence of dust particles in the air does not imply that unhealthy exposures occur. The public health implications of the African dust storms depend on other factors, such as the amount of dust in the air, the duration of the storms, and the relative amounts of chemical and biological contaminants in these dusts.

Regarding the amount of dust in the air, authors of key studies on African dust storms have doubted that the levels of dust alone would exceed EPA's health-based standards for particulate matter (Prospero 1999a). However, they have hypothesized that the amount of African dust in the air, when added to particulate matter from local sources of air pollution, might lead to unhealthy levels of air pollution. This hypothesis has never been verified for Vieques. In fact, none of the particulate sampling studies conducted on Vieques (see Appendix C) have ever shown potentially unhealthy levels of particulate matter, as gauged by EPA's health-based National Ambient Air Quality Standards. Moreover, the historical record of particulate sampling along the eastern shore of the main island of Puerto Rico reveals a similar trend (see Appendix C). These consistent trends among the sampling studies suggest that levels of particulate matter on Vieques have not reached levels that could present a public health hazard, even during African dust storms. This finding should be verified by ongoing review of sampling data collected on the island.

Unfortunately, less information is available on the chemical and biological makeup of dust particles during these African dust storm events. ATSDR has identified studies indicating that the dust particles contain various minerals, and even traces of bacteria and viruses (Griffin et al. 2001). These studies have speculated about potential public health impacts, but no link between adverse health effects and the components of African dust has been established. ATSDR believes its recommendation for sampling of airborne metals (see Section IX) will address the data gap on the mineral content of African dust, and ATSDR supports further research into the type and amounts of biological material (e.g., bacteria, viruses) that may be transported with African dust.

Relative Amounts of Particulate Matter from African Dust Storms and from the LIA

Some community members have asked ATSDR to explain how it is possible that two different sources of air pollution located thousands of miles apart (i.e., the LIA and Africa) can have similar impacts on air quality at Vieques. The key to understanding this issue is that the LIA and African dust storms release dramatically different quantities of particulate matter.

Though emissions from both sources cannot be measured directly, emissions estimates suggest that African dust storms release far more particulate matter to the air than the Navy's military training exercises. Specifically, the Navy has estimated that its operations at Vieques release 70 tons of PM10 to the air per year (IT 2000). On the other hand, researchers have estimated that African dust storms release between 100,000,000 and 1,000,000,000 tons of particulate matter to the air per year (Shinn et al. 2000). Assuming the emissions estimates quoted above are reasonably accurate, the data suggest that African dust storms may release more than 1,000,000 times as much particulate matter as does the LIA.

Therefore, even though the source of African dust is several thousand miles away from Vieques, the fact that African dust storms release dramatically higher levels of particulate matter explains why they can have noticeable impacts on air quality in the Caribbean, even when local sources of air pollution (e.g., the Navy's military training exercises) might have little air quality impacts at distances as short as 7.9 miles from the source.

C. Can ATSDR Provide General Information on Asthma and Air Pollution?

ATSDR's Response: Asthma is a common, and potentially deadly, chronic (or long-term) lung disease. A person with asthma might suffer from "asthma attacks." These attacks can vary in frequency and severity. Some people with asthma have attacks often, while others have them rarely. Less severe asthma attacks result in difficultly breathing, tightness in the chest, coughing, and wheezing. More severe asthma attacks can be life-threatening if a person stops breathing. As a result, it is very important for a person with asthma to get help from a doctor to manage the disease. This is especially important for children with asthma, who have been found to be a sensitive sub-population for acute responses to outdoor air pollution (Clark et al. 1999).

No one has determined exactly what causes some people to have asthma and other people to not have the disease. However, scientists have identified many "asthma triggers" that are known to cause people with asthma to have asthma attacks. Different people are affected by different asthma triggers, and a doctor can help determine which asthma triggers appear to be a problem for a given person. The following list identifies some (but not all) of the known or suspected asthma triggers:

Though outdoor air pollution can trigger asthma attacks, the extent to which outdoor air pollution causes people to have asthma in the first place is unclear. As evidence of this, asthma occurs in areas with relatively low levels of air pollution. Further research is needed to understand to what extent outdoor air pollution affects whether or not a given person has asthma.

ATSDR notes that its review of outdoor air pollution on Vieques was based in part on EPA's health-based National Ambient Air Quality Standards. EPA developed these standards to protect public health, including the health of potentially sensitive populations, like asthmatics. Therefore, ATSDR's analyses found that levels of particulate matter on Vieques do not present a public health hazard, even for people who have asthma. However, ATSDR acknowledges that some asthmatics with extreme sensitivities might have attacks triggered by low levels of pollution. Recognizing that asthma is potentially serious and needs to be treated correctly, ATSDR urges all individuals with asthma–on Vieques and elsewhere in Puerto Rico and the United States–to work with a doctor to set up an asthma management plan. Following such a plan can help keep asthma under control.

Other Community Concerns:

ATSDR is committed to addressing additional community concerns relevant to environmental health issues, as these concerns arise. Vieques residents can direct their health concerns to ATSDR either in writing or via the telephone. Please submit written questions and inquiries to:

Program Evaluation, Records and Information Services Branch
ATSDR, Division of Health Assessment and Consultation
Attn: Isla de Vieques, Puerto Rico
1600 Clifton Road, NE (E-32)
Atlanta, GA 30333

Community members can also call ATSDR either by contacting our regional representatives in New York, New York, at (212) 637-4307 or by calling our toll-free telephone number, 1-888-42-ATSDR (or 1-888-422-8737).


VII. ATSDR CHILD HEALTH INITIATIVE

Because children often are at greater risk than adults for being exposed to toxic chemicals, and because more than 10% of the residential population at Vieques is children (age 6 and under), ATSDR's exposure and public health evaluations for this site specifically considered children's health issues. In general, children are more likely than adults to suffer from adverse health effects due to environmental exposure for several reasons, such as:

For these reasons, ATSDR specifically considered children's health issues in two critical steps of the public health assessment process. First, when comparing levels of air pollution to health-based comparison values (e.g., see Table 4), ATSDR identified comparison values that are protective of children's exposures and of health conditions more common in children (e.g., asthma), to the extent they are available. For instance, ATSDR used EPA's air quality standards for particulate matter and lead when evaluating the air sampling data on Vieques. These standards were developed to protect the health of sensitive populations, including children.

Second, when evaluating scenarios with ambient air concentrations that exceeded or were near to health-based comparison values, ATSDR's toxicological evaluations considered the most current information on health hazards associated with exposures, usually as documented in the "Children's Susceptibility" section of ATSDR's Toxicological Profiles.

With this approach, ATSDR ensured that its review of environmental health issues would consider any specific children's health issues at Vieques. Although ATSDR found that children on Vieques are exposed to environmental contamination from many different sources, the levels of inhalation exposures are far too low to cause adverse health effects. In other words, ATSDR's evaluations found no evidence that chemicals released from the Navy's military training exercises pose any unique health hazards for children. Nonetheless, as a prudent public health measure, ATSDR recommends that air sampling continue to take place at Vieques to ensure that exposures that might present a public health hazard do not occur among the population, including children. Section IX of this report provides more details on this recommendation.


VIII. CONCLUSIONS

This PHA evaluates potential inhalation exposures to air contaminants released from the Navy property on Vieques. ATSDR has been examining, and continues to examine, potential exposures to contamination from other environmental media (e.g., drinking water, soil, and food products). After completing its evaluations, ATSDR will assess the public health implications of the cumulative or overall exposures from the other potential pathways the agency has considered.

For the air exposure pathway, ATSDR concludes the following:

Aware of the level of community health concerns at Vieques, ATSDR is committed to reviewing additional air sampling data and health outcome data as they become available. The Public Health Action Plan (Section IX) outlines future actions that various agencies will take to evaluate environmental health issues at Vieques.


IX. PUBLIC HEALTH ACTION PLAN

The Public Health Action Plan for Vieques describes specific actions that have been taken, are scheduled to take place, or should be taken by numerous parties, including ATSDR, EPA, PREQB, PRDOH, and the Navy. The purpose of this Public Health Action Plan is to ensure that this PHA not only identifies potential public health hazards, but also produces a plan of action to mitigate and prevent harmful human health effects that may be resulting from exposure to hazardous substances in the environment. The following list identifies the public health actions that have been completed, that are ongoing, and that ATSDR recommends take place:

Actions Completed:

Actions Ongoing:

Recommendations for Further Action:

Note: ATSDR's public comment release PHA included several recommendations for further air sampling at Vieques. Since the Navy officially ceased its training exercises on May 1, 2003, ATSDR believes these sampling studies are no longer necessary. The following items list the remaining recommendations that ATSDR believes should be fulfilled.


PREPARERS OF REPORT

Gary Campbell, Ph.D.
Environmental Health Scientist, Section Chief
Federal Facilities Assessment Branch
Division of Health Assessment and Consultation

W. Mark Weber, Ph.D.
Geologist
Federal Facilities Assessment Branch
Division of Health Assessment and Consultation

Gregory M. Zarus, MS
Atmospheric Scientist
Exposure Investigation and Consultation Branch
Division of Health Assessment and Consultation

John Wilhelmi, MS
Senior Chemical Engineer
Eastern Research Group, Inc.


REFERENCES

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ATSDR. 2000a. Toxicological Profile for Arsenic. September 2000.

ATSDR. 2000b. Toxicological Profile for Chromium. September 2000.

ATSDR. 2001a. Focused Petitioned Public Health Assessment: Drinking Water Supplies and Groundwater Pathway Evaluation. October 16, 2001.

ATSDR. 2001b. Petitioned Public Health Assessment: Soil Pathway Evaluation. Public Comment draft. October 23, 2001.

ATSDR. 2001c. Summary Report for the Vieques Heart Study Expert Panel Review. October 2001.

ATSDR. 2001d. Letter to Gladys Gonzalez Martinez (PREQB) from Sandy Isaacs (ATSDR) concerning access to air sampling data for metals. December 19, 2001.

ATSDR. 2001e. Letter to Roberto Rabin (Committee for the Rescue and Development of Vieques) from Sandy Isaacs (ATSDR) concerning access to sampling data for radiation. December 19, 2001.

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EPA. 2002. Ambient air monitoring data accessed from AIRS. Written correspondence between Virginia Ambrose (EPA) and John Wilhelmi (ERG). July 15, 2002.

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TABLES

Table 1. 1990 and 2000 US Census Data for Vieques

Parameter 1990 Census Data 2000 Census Data
Number of Residents Percent of Total Residents Number of Residents Percent of Total Residents
Total residents 8,602 100% 9,106 100%
Men 4,234 49% 4,512 50%
Women 4,368 51% 4,594 50%
Women of childbearing age 1,766 21% 1,701 19%
Children 1,106 13% 1,001 11%
Elderly 993 12% 1,263 14%

Sources of data: US Bureau of the Census 1990, 2000.

Notes:
According to the 1990 census data, 2,056 families lived on Vieques. In 2000, this number increased to 2,366.
Both the 1990 and 2000 census data include residents living on Navy lands and in the residential area.

Definitions:
Women between the ages of 15 and 44 are considered of childbearing age.
Children are residents who are 6 years old or younger.
The elderly includes all residents of age 65 and older.


Table 2. Toxic Release Inventory (TRI) Data for Vieques

Year Name of Facility
(as Listed in TRI)
Chemical Released Air Releases
(pounds per year)
1987 GE Co. Caribe 1,1,1-Trichloroethane 9,314
1988 GE Co. Caribe 1,1,1-Trichloroethane 8,400
1989

No data reported for the island of Vieques

1990

GE Co. Caribe 1,1,1-Trichloroethane 10,900
1991 Caribe GE Distribution Transformers Inc. 1,1,1-Trichloroethane 10,500
1992 Caribe GE Distribution Transformers Inc. Copper 0
1993 Caribe GE Distribution Transformers Inc. Copper 0
1994 Caribe GE Distribution Transformers Inc. Copper 0
1995 Caribe GE Distribution Transformers Inc. Copper 5
1996 GE Power Protection of PR Copper 15
1997 GE Power Protection of PR Copper 30
1998 GE Power Protection of PR Copper 30
1999 GE Power Protection of PR Copper 30

Source of data: EPA 1997, 2001.

Notes:
- The table lists only the air releases that facilities in Vieques reported to TRI.
- For reporting years 1987 through 1995, the "name of facility" is taken from one source of data (EPA 1997); for reporting years 1996 through 1999, it is from another (EPA 2001). Release data for more current years are not yet publicly available.
- TRI data are self-reported; the accuracy of the release data for individual facilities is not known.
- The TRI regulations require facilities in certain industries to disclose releases of specific hazardous chemicals and selected waste management activities. However, the regulations do not require that all facilities report, and do not address all contaminants, which is presumably why the table does not account for other emissions sources on Vieques. Therefore, the data in this table should not be viewed as a comprehensive emissions inventory for Vieques.
- Releases of zero pounds suggest that the facility manufactured, processed, or otherwise used the chemical in large enough quantities to trigger TRI reporting, but none (or less than 0.5 pounds per year) were estimated as being released to the air.


Table 3. Summary of Air Exposure Pathways

Pathway Name Exposure Pathway Elements Time of Exposure Comments
Potential Source of Contamination Environmental Media Point of Exposure Route of Exposure Exposed Population

Potential Exposure Pathways

Inhalation of contaminants in wind-blown dust when bombing did not occur (see Section V.A) Wind-blown dust from the LIA Air: transport from the LIA downwind to residential locations Ambient air Inhalation Residents of Vieques Entire history of Navy operations Extensive sampling collected by PREQB has shown that levels of wind-blown dust on days without military training exercises are not of public health concern.
Inhalation of contaminants released on days when the Navy conducted military training exercises using only practice bombs (see Section V.B) Military training exercises at the LIA using practice bombs Air: transport from the LIA downwind to residential locations Ambient air Inhalation Residents of Vieques Exposures have only occurred on the days between April 1999 and May 1, 2003, when military training exercises occurred. This is limited to no more than 90 days per year. PREQB has collected numerous air samples on days when the Navy conducted training exercises using practice bombs. These samples indicate that levels of particulate matter have not reached levels that could present a public health hazard on days when practice bombs are used. The air sampling results, combined with soil sampling data, also indicate that exposures to metals and explosives are not of health concern on days when practice bombs are used.
Inhalation of contaminants released on days when the Navy conducted military training exercises using live bombs (see Section V.C) Military training exercises at the LIA using live bombs Air: transport from the LIA downwind to residential locations Ambient air Inhalation Residents of Vieques Dates of bombing exercises between 1941 and April 19, 1999 Modeling analyses of reasonable exposure scenarios indicate that the military training exercises involving live bombs did not result in exposures at levels of health concern for all categories of contaminants considered, including particulate matter, chemical by-products of explosions, metals, and explosives.
Inhalation of contaminants released during open burning and open detonation (see Section V.D) Open burning and open detonation of waste munitions and unexploded ordnance Air: transport from the LIA downwind to residential locations Ambient air Inhalation Residents of Vieques On isolated days from at least the early 1970s through the present Modeling analyses of reasonable exposure scenarios indicate that the limited open burning and open detonation activities have not resulted in exposures at levels of health concern for all categories of contaminants considered, including particulate matter, chemical by-products of explosions, metals, and explosives.
Inhalation of contaminants used sporadically during military training exercises (see Section V.D) Past firing of depleted uranium penetrators and ongoing use of chaff. Air: transport from the LIA (for depleted uranium) and in upper air winds patterns (chaff) downwind to residential locations Ambient air Inhalation Residents of Vieques Depleted uranium: limited to the date when the rounds of concern were used, and dates thereafter; chaff: on dates when the Navy uses the material during military training exercises. Modeling analyses of reasonable exposure scenarios indicate that the amounts of depleted uranium that were fired at Vieques and the amounts of chaff that have been released to the air did not result in exposures (either chemical or radiological) at levels of health concern in the residential areas of Vieques.

Note: Indirect exposures to air contaminants in other media (groundwater, soil, biota) are being addressed in other PHAs.


Table 4. Estimates of Annual Average Ambient Air Concentrations of Metals on Vieques When Military Training Exercises Do Not Take Place

Refer to footnotes at the end of the table before interpreting any of the data presented below.
Element Average Concentration of Element in LIA Surface Soils (ppm, by weight) Estimated Annual Average Air Concentration of Element in PM10 (µg/m3) Health-based Comparison Value (µg/m3) Type of Comparison Value
Aluminum 16,200 0.55 3.7 RBC-n
Antimony 1.14 0.00004 1.5 RBC-n
Arsenic 7.87 0.0003 0.0002 CREG
Barium 105 0.004 0.51 RBC-n
Beryllium 0.241 0.000008 0.0004 CREG
Boron 15.7 0.0005 210 RBC-n
Cadmium 1.71 0.00006 0.0006 CREG
Chromium 37.8 0.0013 5500 RBC-n
Cobalt 14.6 0.0005 0.1 EMEG-c
Copper 39.1 0.0013 150 RBC-n
Iron 33,500 1.1 1,100 RBC-n
Lead 8.49 0.0003 1.5 NAAQS
Manganese 723 0.025 0.04 EMEG-c
Mercury 0.0216 0.0000007 0.2 EMEG-c
Nickel 15.9 0.0005 0.2 EMEG-c
Scandium 12.5 0.0004 NA NA
Selenium 1.23 0.00004 180 RBC-n
Strontium 156 0.0053 2200 RBC-n
Tin 4.87 0.0002 2200 RBC-n
Titanium 1,650 0.056 310 RBC-n
Vanadium 106 0.0036 0.2 MRL
Yttrium 20.8 0.0007 NA NA
Zinc 47.5 0.0016 1100 RBC-n
Zirconium 59 0.002 NA NA

Notes:
- The "average concentration of element in LIA surface soils" is taken from ATSDR's previous analysis of soils contamination (ATSDR 2001b).
- The "estimated annual average air concentration of element in PM10" is the product of the values in the first two columns.
- The "estimated annual average air concentration of element in PM10" was calculated by multiplying the annual average air concentration of PM10 in Esperanza (34.1 µg/m3, see Appendix C.1) and the average concentration of the element in LIA soils. This product was divided by 1,000,000 to convert the estimated concentration into units of µg/m3.
- The "type of comparison value" indicates the reference for the comparison value selected (see Appendix A). Abbreviations used in this field are:
    CREG: ATSDR cancer risk evaluation guide
    EMEG-c: ATSDR environmental media evaluation guide for chronic exposure
    MRL: ATSDR Minimal Risk Level
    NAAQS: EPA National Ambient Air Quality Standard
    RBC-n: EPA Region 3 risk-based concentration for noncancer effects
- NA: Scandium, yttrium, and zirconium do not have relevant health-based comparison values.
- The comparison value for "chromium" is for trivalent chromium, not hexavalent chromium. See Section V.A for an interpretation of this selection.


Table 5. Estimates of Annual Average Ambient Air Concentrations of Explosives on Vieques When Military Training Exercises Do Not Take Place

Refer to footnotes at the end of the table before interpreting any of the data presented below.
Chemical Average PM10 Concentration at Esperanza
(µg/m3)
Average Concentration of Chemical in the LIA Soils
(ppm, by weight)
Estimated Annual Average Air Concentration of Chemical in PM10
(µg/m3)
Health-based Comparison Value
(µg/m3)
Type of Comparison Value
2-Amino-4,6-dinitrotoluene 34.1 0.62 0.00002 0.22 RBC-n
HMX 34.1 0.39 0.00001 180 RBC-n
Nitroglycerin 34.1 8.1 0.0003 0.45 RBC-c
RDX 34.1 0.41 0.00001 0.057 RBC-c
TNT 34.1 2.85 0.0001 0.21 RBC-c

Notes:
- The "average PM10 concentration at Esperanza" is based on the PREQB 2000-2002 sampling results (see Appendix C.1).
- The "average concentration of chemical in the LIA soils (ppm, by weight)" is the average concentration of explosives in soil samples collected at the LIA reported in the PHA on soil contamination (ATSDR 2001b).
- The "estimated annual average air concentration of chemical in PM10" is the product of the values in the first two columns.
- The "health-based comparison value" is a toxicity screening value (see Section IV.B and Appendix A for more details).
- The "type of comparison value" indicates the reference for the comparison value selected (see Appendix A). Abbreviations used in this field are:
    RBC-c: EPA Region 3 risk-based concentration for cancer effects
    RBC-n: EPA Region 3 risk-based concentration for noncancer effects


Table 6. Ambient Air Concentrations of Particulate Matter in the Residential Areas of Vieques

Parameter Summary of PREQB's Sampling Results
Data Collected in Esperanza Data Collected in Isabel Segunda
Average Concentration
(µg/m3)
Concentration Range
(µg/m3)
Number of Samples Average Concentration
(µg/m3)
Concentration Range
(µg/m3)
Number of Samples

Summary statistics for total suspended particulates (TSP)

Sampling results for days without military training exercises 41.3 17-163 77 33.0 14-177 79
Sampling results for days with exercises using only practice bombs 53.3 25-124 15 43.8 18-105 10

Summary statistics for particulate matter smaller than 10 microns (PM10)

Sampling results for days without military training exercises 35.0 14-64 75 21.6 10-60 78
Sampling results for days with exercises using only practice bombs 40.1 22-77 13 34.7 11-94 13

Notes:
- Data Source: See Appendix C.1. The data in the table are based on sampling data and range utilization statistics compiled through October 2001. Refer to Table C-1 for a complete account of the sampling results collected since that time.
- Dates with "exercises using only practice bombs" were determined from Navy range utilization statistics. Dates on which air-to-ground or ship-to-shore firing of "non-explosive ordnance" were considered as being exercises using only practice bombs.
- ATSDR ran t-tests to determine if statistically significant differences existed between the average concentrations listed above. These tests revealed that the differences in TSP levels at Esperanza and Isabel Segunda and the differences in PM10 levels at Esperanza were not statistically significant (p-level > 0.05). At Isabel Segunda, the average PM10 concentration during training exercises using practice bombs was greater than the average concentration when no practice bombs were used (p = 0.0005).


Table 7. Correlation Between Weight of Bombs Dropped and Air Sampling Results

Date Total Weight of Non-Explosive Ordnance Used (tons) 24-Hour Average Ambient Air Concentrations Measured by PREQB (µg/m3)
TSP Concentrations in Esperanza TSP Concentrations in Isabel Segunda PM10 Concentrations in Esperanza PM10 Concentrations in Isabel Segunda
8/4/00 0.67 51 No sample 50 No sample
8/16/00 7.03 78 30 No sample 23
10/15/00 2.39 32 24 22 11
5/1/01 1.13 25 24 22 12
6/18/01 12.75 57 No sample 55 39
8/2/01 5.85 45 31 39 No sample
8/3/01 4.80 36 No sample 30 No sample
8/4/01 2.77 56 No sample 47 33
8/6/01 34.01 25 18 22 14
8/7/01 19.06 87 69 77 60
8/8/01 6.17 124 105 No sample 94
9/28/01 12.89 40 43 32 28
10/4/01 1.14 50 51 50 47
10/10/01 0.06 No sample No sample No sample 26
10/11/01 0.28 39 43 33 30
10/12/01 8.42 54 No sample 39 34

Notes:
- Data on weight of practice bombs dropped are taken from the Navy's range utilization statistics (Navy 2002); air sampling data were provided by PREQB (see Appendix C.1). Total weight of non-explosive ordnance used equals the sum of the amounts used for air-to-ground and ship-to-shore exercises. The data in the table are based on sampling data and range utilization statistics compiled through October 2001. Refer to Table C-1 for a complete account of the sampling results collected since that time.
- "No sample" indicates that PREQB did not report a valid sampling result for the pollutant, date, and location indicated.
- The weight of practice bombs dropped on the LIA was essentially uncorrelated with the TSP concentrations at Esperanza (R2 = 0.000), the TSP concentrations at Isabel Segunda (R2 = 0.011), the PM10 concentrations at Esperanza (R2 = 0.002), and the PM10 concentrations at Isabel Segunda (R2 = 0.000).
- Data are presented for only those days when practice bombs were dropped and valid air sampling results were available. Practice bombs were dropped on additional dates not shown in the table, but no valid sampling results were collected on those days.


Table 8. Estimated Annual Average Concentrations of Chemical By-products of Explosions in the Residential Areas of Vieques that Resulted from Live Bombing Exercises

Chemical Estimated Annual Average Ambient Air Concentration (µg/m3) Health-Based Comparison Value (µg/m3) Type of Comparison Value
1,3,5-Trinitrobenzene 0.0000001 110 RBC-n
1,3-Butadiene 0.0000005 0.004 CREG
1,4-Dichlorobenzene 0.00000002 100 EMEG-c
2,4-Dinitrotoluene 0.0000003 7.3 RBC-n
2,6-Dinitrotoluene 0.00000003 3.7 RBC-n
2-Methylphenol 0.00000005 180 RBC-n
4-Methylphenol 0.00000004 18 RBC-n
4-Nitrophenol 0.0000002 29 RBC-n
Acetophenone 0.000001 0.021 RBC-n
Ammonia 0.00002 100 RfC
Benzene 0.00007 0.1 CREG
Benzo(a)pyrene 0.0000003 0.002 RBC-c
Benzyl alcohol 0.00000001 1,100 RBC-n
Biphenyl 0.000000004 180 RBC-n
Bis(2-ethylhexyl)phthalate 0.0000002 0.45 RBC-c
Butylbenzylphthalate 0.00000007 730 RBC-n
Carbon dioxide 0.1 9,000,000 REL
Carbon monoxide 0.0005 10,000 NAAQS
Carbon tetrachloride 0.0000005 0.07 CREG
Dibenz(ah)anthracene 0.0000001 0.00086 RBC-c
Dibenzofurans 0.0000001 150 RBC-n
Diethylphthalate 0.00000003 2,900 RBC-n
Dimethylphthalate 0.00000006 37,000 RBC-n
Di-n-butylphthalate 0.000006 370 RBC-n
Di-n-octylphthalate 0.0000001 73 RBC-n
Diphenylamine 0.000000006 91 RBC-n
Naphthalene 0.00001 10 EMEG-c
Nitric oxide 0.001 370 RBC-n
Nitrogen dioxide 0.0002 100 NAAQS
N-Nitrosodiethylamine 0.000000008 0.00002 CREG
N-Nitrosodiphenylamine 0.0000004 1.3 RBC-n
Phenol 0.000002 2,200 RBC-n
Sulfur dioxide 0.00002 80 NAAQS
Vinyl chloride 0.00000009 0.1 CREG

Notes:
- All estimated annual average ambient air concentrations are based on outputs from ATSDR's air quality modeling analysis (see Appendix D.3). The concentrations listed are the highest estimated levels in the residential areas of Vieques.
- Refer to Appendix D.3 for estimated ambient air concentrations for the 11 chemicals considered in the modeling analysis that do not have health-based comparison values. Estimated concentrations of these chemicals are all considerably lower than levels that air sampling methods can reliably detect.
- Refer to Appendix A for explanations of the abbreviations used to describe the comparison values.


Table 9. Estimated Annual Average Concentrations of Metals in the Residential Areas of Vieques that Resulted from Live Bombing Exercises

Chemical Estimated Annual Average Ambient Air Concentration (µg/m3) Health-Based Comparison Value (µg/m3) Type of Comparison Value
Aluminum 0.02 3.7 RBC-n
Antimony 0.000003 1.5 RBC-n
Arsenic 0.0000004 0.0002 CREG
Barium 0.00006 0.51 RBC-n
Beryllium 0.00000001 0.0004 CREG
Boron 0.0000008 210 RBC-n
Cadmium 0.00009 0.0006 CREG
Chromium (total) 0.00002 5,500 RBC-n
Chromium (hexavalent) 0.0000004 0.00008 CREG
Cobalt 0.0000006 0.03 EMEG-i
Copper 0.003 150 RBC-n
Iron 0.03 2,200 RBC-n
Lead 0.0001 1.5 NAAQS
Manganese 0.0007 0.04 EMEG-i
Mercury 0.00000001 0.2 EMEG-i
Molybdenum 0.0000004 18 RBC-n
Nickel 0.000006 0.2 EMEG-i
Selenium 0.00000005 18 RBC-n
Strontium 0.000007 2,200 RBC-n
Tin 0.0000002 2,200 RBC-n
Titanium 0.0001 31 RBC-n
Vanadium 0.000005 0.2 EMEG-a
Zinc 0.002 1,100 RBC-n

Notes:
- All estimated annual average ambient air concentrations are based on outputs from ATSDR's air quality modeling analysis (see Appendix D.3). The concentrations listed are the highest estimated levels in the residential areas of Vieques.
- Refer to Appendix D.3 for estimated ambient air concentrations for the metals considered in the modeling analysis that do not have health-based comparison values (e.g., calcium). Estimated levels of these chemicals are all considerably lower than air sampling methods can reliably detect.
- Refer to Appendix A for explanations of the abbreviations used to describe the comparison values.


FIGURES

Map of Vieques Vicinity
Figure 1. Map of Vieques Vicinity

Map of Vieques
Figure 2. Map of Vieques

Wind Rose for US Naval Station Roosevelt Roads: 1990-2000
Figure 3. Wind Rose for US Naval Station Roosevelt Roads: 1990-2000

Navy Bombing Statistics I
Figure 4. Navy Bombing Statistics I

Navy Bombing Statistics II
Figure 5. Navy Bombing Statistics II

Air Sampling Locations on Vieques
Figure 6. Air Sampling Locations on Vieques

What Happens When Practice Bombs Are Dropped
Figure 7. What Happens When Practice Bombs Are Dropped

What Happens When Live Bombs Are Dropped
Figure 8. What Happens When Live Bombs Are Dropped

Effect of Live Bombing Exercises on Annual Average PM10 Concentrations on Vieques
Figure 9. Effect of Live Bombing Exercises on Annual Average PM10 Concentrations on Vieques


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