ATSDR-PHA-HC-Organic Chemicals, Inc.-p4

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PUBLIC HEALTH ASSESSMENT

ORGANIC CHEMICALS, INC.
GRANDVILLE, KENT COUNTY, MICHIGAN

APPENDIX A.

FIGURES

LIST OF FIGURES

Figure 1. Site Location

Figure 2. Primary Sources of Contamination

Figure 3. OCI Site Layout

Figure 1. Site Location

Figure 2. Primary Sources of Contamination

Figure 3. Figure 3.OCI Site Layout

APPENDIX B.

TABLES

LIST OF TABLES

Table 1.	Contaminants of concern at the Organic Chemicals site.
Table 2.	Maximum concentrations of contaminants of concern found in groundwater from monitoring wells on the Organic Chemicals site.
Table 3.	Maximum concentrations of contaminants of concern found in surface soil samples collected on the Organic Chemicals site.
Table 4.	Maximum concentrations of contaminants of concern found in sub-surface soil samples collected on the Organic Chemicals site.
Table 5.	Maximum concentrations of contaminants of concern found in groundwater collected from monitoring wells near the Organic Chemicals site.
Table 6.	Concentrations of contaminants in water from residential wells near the Organic Chemicals site, from the RI, 1989-1993.
Table 7.	Maximum concentrations of contaminants of concern found in surface soil samples collected near the Organic Chemicals site.
Table 8.	Maximum concentrations of contaminants of concern found in sub-surface soil samples collected near the Organic Chemicals site.

Table 1. Contaminants of concern at the Organic Chemicals site.

VOLATILE ORGANIC CHEMICALS	OTHER SEMI-VOLATILE ORGANIC CHEMICALS
acetone benzene benzyl alcohol bromomethane chloroethane chloroform chloromethane 1,1-dichloroethane 1,2-dichloroethane 1,1-dichloroethylene 1,2-dichloroethylene ethylbenzene 2-hexanone methylene chloride 4-methyl-2-pentanone styrene tetrachloroethylene toluene 1,1,1-trichloroethane 1,1,2-trichloroethane trichloroethylene vinyl chloride xylenes	bis(2-chloroethyl)ether bis(2-ethylhexyl)phthalate carbazole chlorobenzene di-n-octylphthalate dibenzofuran diethyl phthalate dimethyl phthalate isophorone 2-methylphenol 4-methylphenol nitrobenzene N-nitrosodiphenylamine pentachlorophenol
POLYCYCLIC AROMATIC HYDROCARBONS	METALS AND INORGANIC CHEMICALS
acenaphthylene benzo(a)anthracene benzo(a)pyrene benzo(b)fluoranthene benzo(g,h,i)perylene benzo(k)fluoranthene 2-chloronaphthalene chrysene dibenzo(a,h)anthracene indeno(1,2,3-cd)pyrene 2-methylnaphthalene naphthalene phenanthrene	antimony arsenic barium beryllium cadmium chromium cobalt copper cyanide lead manganese mercury nickel silver thallium vanadium zinc
PESTICIDES AND POLYCHLORINATED BIPHENYLS (PCBs)
aldrin alpha-chlordane dieldrin heptachlor lindane polychlorinated biphenyls (PCBs)

Table 2. Maximum concentrations of contaminants of concern found in groundwater from monitoring wells on the Organic Chemicals site.

Chemical	Date	Maximum Concentration (ppb)	Reference	Comparison Value (ppb)
acetone	1989	1,000.J	2	1,000^R
acetone	1993	ND	6	1,000^R
aldrin	1989	ND	2	0.3^E, 0.002^C
aldrin	1993	0.033J	6	0.3^E, 0.002^C
arsenic	1989	22.5	2	3^E, 0.02^C
arsenic	1993	21.6	6	3^E, 0.02^C
barium	1989	149.J	2	700^R
barium	1993	166.J	6	700^R
benzene	1989	520.J	2	1^C
benzene	1993	155	6	1^C
benzo(b)fluoranthene	1989	ND	2	carcinogen
benzo(b)fluoranthene	1993	2.J	6	carcinogen
benzyl alcohol	1989	970	2	NA
benzyl alcohol	1993	ND	6	NA
beryllium	1989	2.2B	2	0.008^C
beryllium	1993	3.5JB	6	0.008^C
bis(2-ethylhexyl)phthalate	1989	50.J	2	3^C
bis(2-ethylhexyl)phthalate	1993	28	6	3^C
carbazole	1989	ND	2	NA
carbazole	1993	150	6	NA
chlorobenzene	1989	1,500.J	2	200^R
chlorobenzene	1993	205	6	200^R
chloroform	1989	130	2	6^C
chloroform	1993	ND	6	6^C
2-chloronaphthalene	1989	ND	2	NA
2-chloronaphthalene	1993	1.J	6	NA
chromium	1989	32.1	2	10,000^R (III) carcinogen (VI)
chromium	1993	20.9	6	10,000^R (III) carcinogen (VI)
copper	1989	21.2J	2	1,300^MG
copper	1993	28.9J	6	1,300^MG
cyanide	1989	11.7	2	200^R
cyanide	1993	ND	6	200^R
dibenzofuran	1989	7.J	2	NA
dibenzofuran	1993	2.J	6	NA
1,1-dichloroethane	1989	7	2	carcinogen
1,1-dichloroethane	1993	ND	6	carcinogen
1,2-dichloroethane	1989	51.J	2	0.4^C
1,2-dichloroethane	1993	9.J	6	0.4^C
1,1-dichloroethylene	1989	260.J	2	90^E, 0.06^C
1,1-dichloroethylene	1993	39	6	90^E, 0.06^C
1,2-dichloroethylene (total)	1989	1,200.J	2	70^A (cis) 200^R (trans)
1,2-dichloroethylene (total)	1993	565	6	70^A (cis) 200^R (trans)
di-n-octylphthalate	1989	2.J	2	NA
di-n-octylphthalate	1993	3.J	6	NA
ethylbenzene	1989	2,200	2	1,000^R
ethylbenzene	1993	310	6	1,000^R
isophorone	1989	ND	2	4^C
isophorone	1993	4.J	6	4^C
lead	1989	21.4	2	15^PL, carcinogen
lead	1993	1.JB	6	15^PL, carcinogen
manganese	1989	541	2	50^R
manganese	1993	346	6	50^R
mercury	1989	5	2	NA
mercury	1993	ND	6	NA
methylene chloride	1989	9,600	2	5^C
methylene chloride	1993	15	6	5^C
2-methylnaphthalene	1989	55	2	NA
2-methylnaphthalene	1993	25	6	NA
2-methylphenol	1989	51	2	500^R, carcinogen
2-methylphenol	1993	8.J	6	500^R, carcinogen
4-methylphenol	1989	44.J	2	carcinogen
4-methylphenol	1993	12	6	carcinogen
naphthalene	1989	38.J	2	20^A
naphthalene	1993	13	6	20^A
nickel	1989	15.7J	2	carcinogen
nickel	1993	40.9	6	carcinogen
N-nitrosodiphenylamine	1989	1,600	2	7^C
N-nitrosodiphenylamine	1993	160	6	7^C
pentachlorophenol	1989	23.J	2	0.3^C
pentachlorophenol	1993	4.J	6	0.3^C
phenanthrene	1989	7.J	2	NA
phenanthrene	1993	7.J	6	NA
silver	1989	ND	2	50^R
silver	1993	45.5J	6	50^R
tetrachloroethylene	1989	2,500	2	0.7^C
tetrachloroethylene	1993	1.J	6	0.7^C
toluene	1989	53,000	2	2,000^R
toluene	1993	660	6	2,000^R
1,1,1-trichloroethane	1989	4.J	2	200^A
1,1,1-trichloroethane	1993	ND	6	200^A
trichloroethylene	1989	33,000	2	3^C
trichloroethylene	1993	195	6	3^C
vanadium	1989	30.J	2	NA
vanadium	1993	ND	6	NA
vinyl chloride	1989	160.J	2	0.2^E, carcinogen
vinyl chloride	1993	11	6	0.2^E, carcinogen
xylenes (total)	1989	6,800	2	2,000^Ei
xylenes (total)	1993	3,450	6	2,000^Ei
zinc	1989	45.2	2	3,000^R
zinc	1993	13.8	6	3,000^R

Chemicals not detected in this medium during either round of sampling are not listed.

Shaded chemicals exceed comparison values.

ND -- Not Detected
B -- Analyte Detected in Laboratory Blank Sample
J -- Estimated Value

(cis)-- cis- isomer
(trans)-- trans- isomer

(III)-- For chromium(III)
(VI)-- For chromium(VI)

NA -- None Available
carcinogen -- Carcinogen (proven, probable, or possible) but no CREG available

Comparison Value Bases

E -- ATSDR Environmental Media Evaluation Guide (EMEGs)
Ei -- ATSDR Environmental Media Evaluation Guide, Intermediate-term exposure
C -- ATSDR Cancer Risk Evaluation Guide (CREGs)
A -- U.S. EPA Drinking Water Health Advisory (Lifetime)
MG -- U.S. EPA Safe Drinking Water Act Maximum Contaminant Level Goal
R -- Reference Dose Media Evaluation Guide (RMEGs), calculated from U.S. EPA Reference Dose (Chronic) by Ingestion, based on 10 kilogram child drinking 1 liter per day of water per day.
PL -- U.S. EPA Proposed Action Level for Lead in Drinking Water

Table 3. Maximum concentrations of contaminants of concern found in surface soil samples collected on the Organic Chemicals site.

Chemical	Date	Maximum Concentration (ppm)	Reference	Comparison Value (ppm)
acenaphthylene	1989	ND	2	NA
acenaphthylene	1993	0.31J	6	NA
acetone	1989	ND	2	200^R
acetone	1993	0.08J	6	200^R
aldrin	1989	0.073J	2	0.06^E, 0.04^C
aldrin	1993	ND	6	0.06^E, 0.04^C
arsenic	1989	7	2	0.6^E, 0.4^C
arsenic	1993	6.4	6	0.6^E, 0.4^C
barium	1989	262	2	100^R
barium	1993	2,180	6	100^R
benzene	1989	0.009	2	20^C
benzene	1993	0.005J	6	20^C
benzo(a)anthracene	1989	5.4	2	carcinogen
benzo(a)anthracene	1993	2.1J	6	carcinogen
benzo(b)fluoranthene	1989	5.9	2	carcinogen
benzo(b)fluoranthene	1993	3.7J	6	carcinogen
benzo(k)fluoranthene	1989	2.6	2	carcinogen
benzo(k)fluoranthene	1993	3.2	6	carcinogen
benzo(g,h,i)perylene	1989	4.2	2	NA
benzo(g,h,i)perylene	1993	1.7	6	NA
benzo(a)pyrene	1989	21	2	0.1^C
benzo(a)pyrene	1993	2	6	0.1^C
beryllium	1989	2.5	2	0.2^C
beryllium	1993	ND	6	0.2^C
bis(2-ethylhexyl)phthalate	1989	75	2	40^R
bis(2-ethylhexyl)phthalate	1993	220	6	40^R
cadmium	1989	10.6	2	1^E, carcinogen
cadmium	1993	ND	6	1^E, carcinogen
carbazole	1989	ND	2	NA
carbazole	1993	0.63	6	NA
alpha-chlordane	1989	0.031	2	0.03^C
alpha-chlordane	1993	ND	6	0.03^C
chloroform	1989	ND	2	20^E, 100^C
chloroform	1993	0.001J	6	20^E, 100^C
chromium	1989	228	2	2,000^R (III) carcinogen (VI)
chromium	1993	1,590	6	2,000^R (III) carcinogen (VI)
chrysene	1989	39	2	carcinogen
chrysene	1993	2.1	6	carcinogen
cobalt	1989	31.3	2	NA
cobalt	1993	59.2	6	NA
copper	1989	189	2	NA
copper	1993	526	6	NA
cyanide	1989	18	2	40^R
cyanide	1993	136	6	40^R
dibenzo(a,h)anthracene	1989	ND	2	carcinogen
dibenzo(a,h)anthracene	1993	0.25J	6	carcinogen
dibenzofuran	1989	0.053J	2	NA
dibenzofuran	1993	0.21J	6	NA
1,1-dichloroethylene	1989	ND	2	20^E, 1^C
1,1-dichloroethylene	1993	0.018	6	20^E, 1^C
1,2-dichloroethylene (total)	1989	ND	2	NA (cis) 40^R (trans)
1,2-dichloroethylene (total)	1993	13	6	NA (cis) 40^R (trans)
dieldrin	1989	0.22	2	0.1^E, 0.04^C
dieldrin	1993	ND	6	0.1^E, 0.04^C
dimethyl phthalate	1989	ND	2	NA
dimethyl phthalate	1993	0.69	6	NA
di-n-octylphthalate	1989	23	2	NA
di-n-octylphthalate	1993	11	6	NA
ethylbenzene	1989	950	2	200^R
ethylbenzene	1993	25	6	200^R
indeno(1,2,3-cd)pyrene	1989	4.9	2	carcinogen
indeno(1,2,3-cd)pyrene	1993	1.4J	6	carcinogen
isophorone	1989	ND	2	400^R, 70^C
isophorone	1993	0.18J	6	400^R, 70^C
lead	1989	1,160	2	carcinogen
lead	1993	13,100	6	carcinogen
lindane	1989	0.0036J	2	0.6^C
lindane	1993	ND	6	0.6^C
manganese	1989	1,060	2	300^R
manganese	1993	2,010	6	300^R
mercury	1989	3.6	2	NA
mercury	1993	1.6	6	NA
methylene chloride	1989	1,100	2	100^E, 90^C
methylene chloride	1993	0.005J	6	100^E, 90^C
2-methylnaphthalene	1989	2.1J	2	NA
2-methylnaphthalene	1993	1.6	6	NA
naphthalene	1989	9.8	2	NA
naphthalene	1993	1.4J	6	NA
nickel	1989	34.4	2	carcinogen
nickel	1993	75.4	6	carcinogen
nitrobenzene	1989	ND	2	1^R
nitrobenzene	1993	0.99J	6	1^R
N-nitrosodiphenylamine	1989	17	2	100^C
N-nitrosodiphenylamine	1993	3.J	6	100^C
phenanthrene	1989	33	2	NA
phenanthrene	1993	3.1	6	NA
polychlorinated biphenyls (PCBs)	1989	14	2	0.04^E, 0.09^C
polychlorinated biphenyls (PCBs)	1993	ND	6	0.04^E, 0.09^C
tetrachloroethylene	1989	66	2	10^C
tetrachloroethylene	1993	9.8	6	10^C
toluene	1989	6,700	2	400^R
toluene	1993	74	6	400^R
1,1,1-trichloroethane	1989	ND	2	NA
1,1,1-trichloroethane	1993	0.009J	6	NA
trichloroethylene	1989	0.038	2	60^C
trichloroethylene	1993	3	6	60^C
vanadium	1989	31.1	2	NA
vanadium	1993	29.9	6	NA
xylenes (total)	1989	7,300	2	400^Ei
xylenes (total)	1993	73.J	6	400^Ei
zinc	1989	226	2	600^R
zinc	1993	598.J	6	600^R

Chemicals not detected in this medium during either round of sampling are not listed.

Shaded chemicals exceed comparison values.

ND -- Not Detected
B -- Analyte Detected in Laboratory Blank Sample
J -- Estimated Value

(cis)-- cis- isomer
(trans)-- trans- isomer

(III)-- For chromium(III)
(VI)-- For chromium(VI)

NA -- None Available
carcinogen -- Carcinogen (proven, probable, or possible) but no CREG available

Comparison Value Bases

E -- ATSDR Environmental Media Evaluation Guide (EMEGs)
Ei -- ATSDR Environmental Media Evaluation Guide, Intermediate-term exposure
C -- ATSDR Cancer Risk Evaluation Guide (CREGs)
R -- Reference Dose Media Evaluation Guide (RMEGs), calculated from U.S. EPA Reference Dose (Chronic) by Ingestion, based on 10 kilogram child subject to pica behavior

Table 4. Maximum concentrations of contaminants of concern found in sub-surface soil samples collected on the Organic Chemicals site.

Chemical	Date	Maximum Concentration (ppm)	Reference	Comparison Value (ppm)
acetone	1989	ND	2	200^R
acetone	1993	2.6J	6	200^R
arsenic	1989	3.7	2	0.6^E, 0.4^C
arsenic	1993	9.9	6	0.6^E, 0.4^C
barium	1989	163	2	100^R
barium	1993	120.J	6	100^R
benzene	1989	ND	2	20^C
benzene	1993	0.33	6	20^C
benzo(a)anthracene	1989	ND	2	carcinogen
benzo(a)anthracene	1993	7.2	6	carcinogen
benzo(b)fluoranthene	1989	ND	2	carcinogen
benzo(b)fluoranthene	1993	9.4X	6	carcinogen
benzo(k)fluoranthene	1989	ND	2	carcinogen
benzo(k)fluoranthene	1993	9.4X	6	carcinogen
benzo(g,h,i)perylene	1989	ND	2	NA
benzo(g,h,i)perylene	1993	3.5J	6	NA
benzo(a)pyrene	1989	ND	2	0.1^C
benzo(a)pyrene	1993	5.2	6	0.1^C
beryllium	1989	1.6	2	0.2^C
beryllium	1993	1.3	6	0.2^C
bis(2-ethylhexyl)phthalate	1989	47	2	40^R
bis(2-ethylhexyl)phthalate	1993	14	6	40^R
cadmium	1989	4	2	1^E, carcinogen
cadmium	1993	1.9	6	1^E, carcinogen
carbazole	1989	ND	2	NA
carbazole	1993	1.7J	6	NA
chlorobenzene	1989	94	2	40^R
chlorobenzene	1993	0.12	6	40^R
chloroform	1989	ND	2	20^E, 100^C
chloroform	1993	0.79J	6	20^E, 100^C
chromium	1989	194	2	2,000^R (III) carcinogen (VI)
chromium	1993	189.2	6	2,000^R (III) carcinogen (VI)
chrysene	1989	ND	2	carcinogen
chrysene	1993	5.7	6	carcinogen
cobalt	1989	7.2J	2	NA
cobalt	1993	10.3J	6	NA
copper	1989	46.4	2	NA
copper	1993	76	6	NA
cyanide	1989	ND	2	40^R
cyanide	1993	4.0	6	40^R
dibenzo(a,h)anthracene	1989	ND	2	carcinogen
dibenzo(a,h)anthracene	1993	1.2J	6	carcinogen
dibenzofuran	1989	ND	2	NA
dibenzofuran	1993	0.6J	6	NA
1,1-dichloroethane	1989	ND	2	carcinogen
1,1-dichloroethane	1993	0.006J	6	carcinogen
1,2-dichloroethane	1989	ND	2	8^C
1,2-dichloroethane	1993	0.002J	6	8^C
1,1-dichloroethylene	1989	ND	2	20^E, 1^C
1,1-dichloroethylene	1993	0.005J	6	20^E, 1^C
1,2-dichloroethylene (total)	1989	ND	2	NA (cis) 40^R (trans)
1,2-dichloroethylene (total)	1993	0.017	6	NA (cis) 40^R (trans)
diethyl phthalate	1989	ND	2	1,000^R
diethyl phthalate	1993	0.22	6	1,000^R
dimethyl phthalate	1989	ND	2	NA
dimethyl phthalate	1993	0.73	6	NA
di-n-octylphthalate	1989	0.15J	2	NA
di-n-octylphthalate	1993	1.3J	6	NA
ethylbenzene	1989	93	2	200^R
ethylbenzene	1993	38	6	200^R
2-hexanone	1989	ND	2	NA
2-hexanone	1993	0.005J	6	NA
indeno(1,2,3-cd)pyrene	1989	ND	2	carcinogen
indeno(1,2,3-cd)pyrene	1993	4.5	6	carcinogen
lead	1989	959	2	carcinogen
lead	1993	631.J	6	carcinogen
manganese	1989	316	2	300^R
manganese	1993	808.J	6	300^R
mercury	1989	0.16	2	NA
mercury	1993	7.8	6	NA
methylene chloride	1989	ND	2	100^E, 90^C
methylene chloride	1993	0.66J	6	100^E, 90^C
2-methylnaphthalene	1989	0.17J	2	NA
2-methylnaphthalene	1993	0.66	6	NA
4-methyl-2-pentanone	1989	ND	2	NA
4-methyl-2-pentanone	1993	0.097	6	NA
2-methylphenol	1989	ND	2	100^R, carcinogen
2-methylphenol	1993	0.048J	6	100^R, carcinogen
4-methylphenol	1989	ND	2	carcinogen
4-methylphenol	1993	0.1J	6	carcinogen
naphthalene	1989	12.J	2	NA
naphthalene	1993	0.76	6	NA
nickel	1989	62.8	2	carcinogen
nickel	1993	25.6	6	carcinogen
N-nitrosodiphenylamine	1989	240	2	100^C
N-nitrosodiphenylamine	1993	2.0J	6	100^C
phenanthrene	1989	0.32J	2	NA
phenanthrene	1993	12	6	NA
polychlorinated biphenyls (PCBs)	1989	3.5	2	0.04^E, 0.09^C
polychlorinated biphenyls (PCBs)	1993	5.6	6	0.04^E, 0.09^C
styrene	1989	16	2	carcinogen
styrene	1993	ND	6	carcinogen
tetrachloroethylene	1989	2.5	2	10^C
tetrachloroethylene	1993	0.79	6	10^C
toluene	1989	1,800	2	400^R
toluene	1993	61	6	400^R
1,1,1-trichloroethane	1989	ND	2	NA
1,1,1-trichloroethane	1993	0.025J	6	NA
1,1,2-trichloroethane	1989	ND	2	8^R
1,1,2-trichloroethane	1993	11	6	8^R
trichloroethylene	1989	100	2	60^C
trichloroethylene	1993	0.11	6	60^C
vanadium	1989	34.9	2	NA
vanadium	1993	27.7	6	NA
xylenes (total)	1989	360	2	400^Ei
xylenes (total)	1993	250	6	400^Ei
zinc	1989	199	2	600^R
zinc	1993	170	6	600^R

Chemicals not detected in this medium during either round of sampling are not listed.

Shaded chemicals exceed comparison values.

ND -- Not Detected
B -- Analyte Detected in Laboratory Blank Sample
J -- Estimated Value
X -- Benzo(b)fluoranthene and benzo(k)fluoranthene were not separable

(cis)-- cis- isomer
(trans)-- trans- isomer

(III)-- For chromium(III)
(VI)-- For chromium(VI)

NA -- None Available
carcinogen -- Carcinogen (proven, probable, or possible) but no CREG available

Comparison Value Bases

E -- ATSDR Environmental Media Evaluation Guide (EMEGs)
Ei -- ATSDR Environmental Media Evaluation Guide, Intermediate-term exposure
C -- ATSDR Cancer Risk Evaluation Guide (CREGs)
R -- Reference Dose Media Evaluation Guide (RMEGs), calculated from U.S. EPA Reference Dose (Chronic) by Ingestion, based on 10 kilogram child subject to pica behavior

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