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HEALTH CONSULTATION

CERTAIN-TEED CORPORATION
EAST ST. LOUIS, ST. CLAIR COUNTY, ILLINOIS


APPENDICES

Table 1 Summary of Soil Samples During Investigations of the Certain-Teed Corporation Site

Table 2 Contaminants of Concern in Soil Samples Collected from On-Site and Off-Site Areas

Table 3 Estimated Soil Exposures in Workers and Children to Soil Contaminants

Table 4 Completed Exposure Pathway Information

Figure 1 Site Location Map

Figure 2 Soil Sample Location Map

Attachment 1 Description of Sampling Locations

Attachment 2 Exposure Dose Calculations


Table 1.

Summary of Soil Samples taken at Certain-teed (in parts per million)
Compound/CV X101 X102 X103 X104 X105 X106 X107 X108 X109 X110 X111 X112
SEMIVOLATILES
4-Methylphenol 0 0.15 0 0.005 0 0 0 0 0 0 0 0
Isophorone 0 0 0 0.02 0 0 0 0 0 0 0 0
Naphthalene 0.017 0.12 0.009 0.076 0.15 2.6 0.024 0.059 0.026 0.069 0.09 0
4-Chloroaniline 0 0 0.048 0 0 0 0 0 0 0 0 0
2-Methylnaphthalene 0.024 0.28 0.016 0.11 0.24 2.8 0.03 0.055 0.046 0.17 0.12 0.34
Dimethylphthalate 0 0 0 0.006 0 0 0 0 0 0 0 0
Acenaphthylene 0 0.077 0.008 0.042 0.034 0.35 0.066 0.039 0.025 0.03 0.04 0
Acenaphthalene 0.019 0.021 0.008 0.072 0.15 2.6 0.01 0.057 0.019 0.1 0.11 0
Dibenzofuran 0.018 0.055 0.009 0.096 0.14 2.1 0.02 0.063 0.029 0.096 0.092 0.18
Diethylphthalate 0.007 0 0.017 0.015 0 0.16 0.013 0.018 0.013 0.013 0.015 0
Fluorene 0.015 0.024 0.009 0.11 0.13 2.1 0.008 0.047 0.017 0.093 0.099 0
N-Nitrosodiphenylamine 0 0.073 0 0.017 0.04 0.27 0 0 0 0.038 0.026 0
Phenanthrene 0.26 0.61 0.15 1.2 2.4 31 0.23 0.74 0.43 1.4 1.9 0.83
Anthracene 0.047 0.17 0.024 0.26 0.4 6.4 0.048 0.15 0.089 0.18 0.3 0
Carbazole 0.023 0 0.017 0.14 0.32 4.1 0.043 0.08 0.046 0.19 0.15 0
Di-n-butylphthalate 0 0 0 0 0 0.22 0 0 0 0 0 0.4
Fluoranthene 0.41 1.3 0.26 1.8 3.6 41 0.74 1 0.64 1.8 2.9 0.91
Pyrene 0.35 1.2 0.19 1.1 3.1 34 0.56 0.69 0.43 1.2 2.2 0.83
Butylbenzylphthalate 0 0 0.025 6.4 0 0 0.024 0.024 0.034 0.026 0.041 0
Benz(a)Anthracene 0.2 0.39 0.11 0.7 1.8 19 0.36 0.4 0.25 0.74 1.3 0.44
Chrysene 0.22 1 0.14 0.48 2.1 20 0.47 0.44 0.31 0.84 1.6 0
bis(2-Ethylhexy 1)phthalate 0 0 0 1.3 0 0.38 0 0 0 0 0 0
Benzo(b)Fluoranthene 0.26 1.9 0.27 1.4 3 24 1.1 0.84 0.66 1.6 2.5 0.62
Benzo(k)Fluoranthene 0.13 0 0.1 0.66 1.7 6.5 0.46 0.48 0.32 0.81 1.3 0
Benzo(a)Pyrene 0.17 0 0.11 0.54 1.4 17 0.41 0.33 0.22 0.5 1.1 0.37
Indeno(1,2,3-cd)Pyrene 0.16 0.57 0 0.36 0.97 15 0.3 0.25 0.19 0.37 0.69 0.64
Dibenz(a,h)anthracene 0.045 0 0 0.096 0 0.7 0 0 0 0 0.21 0
Benzo(g,h,i)Perylene 0.084 0.4 0 0.2 0.75 12 0.24 0.2 0.13 0.16 0.32 1.4
PESTICIDES/PCBs
alpha-BHC 0 0 0 0 0 0.0028 0 0 0 0 0.0013 0
delta-BHC 0.00027 0.0043 0 0.001 0 0 0 0 0 0 0 0
gamma-BHC (Lindane) 0.00015 0 0 0.00017 0 0 0 0 0 0.00096 0.0004 0
Heptachlor 0 0 0 0.00083 0 0.0035 0 0 0 0 0 0.0025
Aldrin 0.0013 0.024 0 0 0 0 0 0.004 0.0032 0 0.0071 0
Heptachlor epoxide 0 0.12 0 0.031 0 0 0.0063 0.031 0 0 0 0
Endosulfan I 0 0 0 0 0.006 0.019 0 0.03 0 0 0.0015 0.0025
Dieldrin 0.12 0.039 0.0017 0.03 0.014 0.29 0.02 0.095 0.066 0.042 0.012 0.88
4,4'-DDE 0.026 0.16 0.0032 0.06 0.043 0.11 0.012 0.041 0.024 0.066 0.028 0.022
Endrin 0.0015 0.029 0.0009 0.0095 0.0055 0.024 0.0023 0.0079 0.0036 0.0024 0.0011 0.016
4,4'-DDD 0.0032 0.049 0.0011 0.011 0.017 0.035 0.0022 0 0 0.032 0.0055 0.031
4,4'-DDT 0.047 0.12 0.0027 0.056 0.032 0.11 0.0073 0.019 0.011 0.24 0.049 0.086
Methoxychlor (Mariate) 0.0052 0 0.0024 0.011 0.059 0.15 0.0062 0.024 0 0 0.019 0
Endrin Ketone 0.0014 0.031 0.0013 0.0037 0.024 0.077 0.002 0.01 0 0.502 0.0099 0.016
Endrin Aldehyde 0 0 0 0 0 0.058 0 0 0 0 0.014 0
alpha-Chlorodane 0.0012 0.025 0.00091 0.0087 0.0025 0.0097 0.0024 0.017 0.0061 0.011 0 0.021
gamma-Chlorodane 0.00063 0.056 0.0012 0.0096 0 0 0.002 0.007 0.0053 0.0083 0.0022 0.015
Arochlor-1254 0 2.8 0 0 0 0 0 0 0 0 0 0
Arochlor-1260 0 1.8 0.31 2.7 0 0 0.64 1.2 0.76 0 0.22 0
INORGANICS
Aluminum 16.8 4.49 1.92 4.91 9.94 5.42 7.82 9.75 8.76 9.55 7.65 9.44
Arsenic 0.0118 0.01 0.0028 0.0077 0.0074 0.0264 0.029 0.0105 0.0099 0.0177 0.0086 0.0141
Barium 0.251 0.123 0.0347 0.136 0.14 0.119 0.324 0.257 0.504 0.335 0.159 0.277
Beryllium 0.0013 0 0 0.0004 0.0012 0.00085 0.00084 0.00049 0.00048 0.0014 0.00056 0.00063
Cadmium 0.0048 0.0157 0.002 0.0045 0.0021 0.0042 0.0069 0.0027 0.0017 0.0057 0.0025 0.0043
Calcium 9.21 15.3 3.95 105 43.2 19 18.2 40 34.1 9.4 35.9 16
Chromium 0.0254 0.0805 0.0089 0.132 0.0274 0.025 0.0717 0.0828 0.0781 0.0266 0.0196 0.0253
Cobalt 0.0094 0.0136 0.0033 0.0049 0.0061 0.0065 0.0116 0.0076 0.0074 0.0235 0.0067 0.0079
Copper 0.0584 0.139 0.111 0.123 0.0562 0.0749 0.249 0.0946 0.0806 0.103 0.0445 0.0724
Iron 25.1 16.8 5.36 35.3 18.7 30.6 87.1 20.6 19.1 36.4 17.7 24.5
Lead 0.223 0.547 0.0646 0.63 0.157 0.195 0.377 0.156 0.121 0.557 0.215 3.32
Magnesium 5.16 13.6 1.2 10.3 3.26 2.79 2.37 3.35 2.78 1.48 10.6 2.23
Manganese 0.66 0.454 0.167 3.26 0.275 0.362 1.24 0.374 0.261 1.66 0.481 0.458
Mercury 0.00015 0.00067 0.0095 0.00086 0.00019 0.002 0.00053 0.00017 0.00016 0.00061 0.00014 0.00032
Nickel 0.024 0.0591 0.0107 0.0169 0.03 0.0265 0.0441 0.0426 0.0396 0.0297 0.0177 0.0212
Potassium 3.93 0.526 0.318 1.01 1.94 0.774 1.14 1.67 1.7 1.81 1.64 1.97
Selenium 0.00096 0.001 0 0 0 0.0012 0.0021 0 0 0.0013 0.00073 0.0014
Silver 0.002 0.0013 0 0.0018 0.00097 0.0017 0.0056 0.0011 0 0.0021 0.00081 0.0016
Sodium 0.304 0.432 0.22 0.437 2 0.579 0.618 1.04 1.06 0.442 0.389 0.492
Thallium 0.0012 0.00088 0 0 0 0.0014 0.0034 0 0 0.0018 0 0.0013
Vanadium 0.0446 0.0307 0.006 0.163 0.0592 0.0282 0.0579 0.0539 0.0551 0.0386 0.0292 0.0298
Zinc 0.44 4.24 0.23 0.593 0.287 0.506 1.4 0.429 0.397 1.26 0.339 2.7
Cyanide 0 0 0 0 0 0.0007 0 0 0 0 0 0.0014


Table 2.

Contaminants of Concern (in parts per million)
Compound/CV X101 X102 X103 X104 X105 X106 X107 X108 X109 X110 X111 X112

Soil ppm

Source
BCKGND ONSITE ONSITE ONSITE ONSITE ONSITE ONSITE ONSITE ONSITE RES RES RES
SEMIVOLATILES
Naphthalene 0.017J 0.12J 0.009J 0.076J 0.15J 2.6J 0.024J 0.059J 0.026J 0.069J 0.09J ND NONE NONE
2-Methylnaphthalene 0.024J 0.28J 0.016J 0.11J 0.24J 2.8J 0.03J 0.055J 0.046J 0.17J 0.12J 0.34J NL NL
Acenaphthalene 0.019J 0.021J 0.008J 0.072J 0.15J 2.6J 0.01J 0.057J 0.019J 0.1J 0.11J ND NL NL
Dibenzofuran 0.018J 0.055J 0.009J 0.096J 0.14J 2.1J 0.02J 0.063J 0.029J 0.096J 0.092J 0.18J NL NL
Phenanthrene 0.26J 0.61 0.15J 1.2 2.4 31 0.23J 0.74 0.43 1.4 1.9 0.83J NL NL
Carbazole 0.023J ND 0.017J 0.14J 0.32J 4.1J 0.043J 0.08J 0.046J 0.19J 0.15J ND NL NL
Benz(a)Anthracene 0.2J 0.39J 0.11J 0.7 1.8 19 0.36J 0.4J 0.25J 0.74 1.3 0.44J NONE NONE
Chrysene 0.22J 1 0.14J 0.48 2.1 20B 0.47 0.44J 0.31J 0.84 1.6 ND NONE NONE
bis(2-Ethylhexyl)phthalate ND ND ND 1.3B ND 0.38J ND ND ND ND ND ND NL NL
Benzo(b)Fluoranthene 0.26J 1.9 0.27J 1.4 3 24 1.1 0.84 0.66 1.6 2.5 0.62J NONE NONE
Benzo(k)Fluoranthene 0.13J ND 0.1J 0.66 1.7D 6.5J 0.46 0.48J 0.32J 0.81 1.3 ND NONE NONE
Benzo(a)Pyrene 0.17J ND 0.11J 0.54 1.4 17 0.41J 0.33J 0.22J 0.5 1.1 0.37J 0.1 CREG
Indeno(1,2,3-cd)Pyrene 0.16J 0.57J ND 0.36J 0.97 15 0.3J 0.25J 0.19J 0.37 0.69 0.64J NONE NONE
Dibenz(a,h)anthracene 0.045J ND ND 0.096J ND 0.7J ND ND ND ND 0.21J ND NONE NONE
Benzo(g,h,i)Perylene 0.084J 0.4J ND 0.2J 0.75 12J 0.24J 0.2J 0.13J 0.16J 0.32J 1.4J NONE NONE
PESTICIDES/PCBs
Heptachlor epoxide ND 0.12JP ND 0.031JP ND ND 0.0063JP 0.031JP ND ND ND ND 0.08 CREG
Dieldrin 0.12D 0.039JP 0.0017JP 0.03JPD 0.014JP 0.29JPD 0.02P 0.095JPD 0.066 0.042JPD 0.012P 0.88D 0.04 CREG
Arochlor-1254 ND 2.8P ND ND ND ND ND ND ND ND ND ND 0.04/1/10 RMEG
Arochlor-1260 ND 1.8P 0.31 2.7D ND ND 0.64 1.2P 0.76P ND 0.22P ND 0.01/0.3 C EMEG
INORGANICS
Arsenic 11.8 10 2.8 7.7 7.4 26.4 29 10.5 9.9 17.7 8.6 14.1 0.6/20/200 C EMEG
Beryllium 1.3 ND ND 0.4B 1.2B 0.85B 0.84B 0.49B 0.48B 1.4 0.56B 0.63B 0.2 CREG
Lead 223 547 64.6 630 157 195 377 156 121 557 215 3320 NONE NONE
Mercury 0.15 0.67 9.5 0.86 0.19 2 0.53 0.17 0.16 0.61 0.14 0.32 NONE NONE
Thallium 1.2 0.88 ND ND ND 1.4 3.4 ND ND 1.8 ND 1.3 NONE NONE
J= estimated value, qualitatively correct but quantitatively suspect
P=alternate analytical method used to analyze for this compound
EMEG - Chronic Environmental Evaluation Guide
B=analyte found in the associated blank
and indicates possible/probable blank contamination
ND = Not Detected
CREG=Carcinogenic Risk Evaluation Guideline for
1 X 10-6 excess cancer risk
NL - chemical not listed in ATSDR comparison values
EMEG=Environmental Media Evaluation Guide
D - analyzed at a secondary dilution factor

Table 3.

Estimated Soil Exposure in Workers and Children
Compound/CV Concentration Range in Onsite Soils (in ppm) Workers Exposure to Onsite Soil (using Maximum) Concentration Range in Offsite Soils (in ppm) Childs Exposure to Offsite Soil Comparison Values in Soil Exceeded EPAs Oral Slope Factor Cancer Risk
Health Guidelines (mg/kg/day) Source Workers Children Workers Children
SEMIVOLATILES
Benzo(a)pyrene D-1.4 5.8 X 10-7 0.37J-1.1 1.1 X 10-5 0.1 A Oral MRL NO NO 7.3 4.2 X 10-5 8 X 10-5
PESTICIDES/PCBs
Heptachlor epoxide D-0.12 5.3 X 10-7 D 0 0.000013 C.O.MRL NO NO 9.1 4.8 X 10-7 0
Dieldrin 0.0017JP-0.29JPD 1.2 X 10-7 0.012P-0.88D 8.8 X 10-6 0.00005 C.O.MRL NO NO 16 1.9 X 10-6 1.4 X 10-4
Arochlor-1254* D-2.8P 1.2 X 10-6 D 0 0.00002 C.O.Rfd NO NO None/0/05(1) 6 X 10-8 0
Arochlor-1260* D-2.7D 1.1 X 10-6 D-0.22P 2.2 X 10-6 0.00002 C.O.MRL NO NO 0.05 5.5 X 10-8 1.1 X 10-7
INORGANICS
Arsenic 2.8-29 1.2 X 10-5 8.6-17.7 1.8 X 10-4 C.O.MRL 0.0003 NO NO 1.5 1.8 X 10-5 2.7 X 10-4
Beryllium D-1.3 5.3 X 10-7
4.14 X 10-7
D-1.8 1.8 X 10-5 C.O.RFD 0.005 NO NO 4.3 2.3 X 10-6 7.7 X 10-5
mg/kg/day = milligrams per kilogram per day
MRL = Minimal Risk Level
* - There was not a slope factor for Arochlor-1254 so the slope factor for PCBs was used.
A. Oral MRL - Acute Oral MRL
D - Not Detected in Sample
RFD=Reference Dose
J=estimated value, qualitatively correct but quantitatively suspect
P=alternate analytical method used to analyze for this compound
C. O. MRL - Chronic Oral MRL

Table 4.

Completed Exposure Pathways - Certain-Teed Site
Pathway Name: Source Medium Exposure
Point
Exposure
Route
Receptor
Population
Time of
Exposure
Exposure
Activities
Estimated Number Exposed Chemicals
On-site Surface Soil Surface Wastes Surface Soil Individuals on the site Ingestion
Inhalation
Dermal
On-site Workers
Trespassers
Past
Present
Future
Working/trespassing on the site. 10 Table 2
Off-site Surface Soil Soil Surface Soil Residential Yards Ingestion
Inhalation
Dermal
Residents Past
Present
Future
Contacting Soil 40 Table 2


Figure 1. Certain-teed Corporation Site Location Map


Figure 2. Soil Sample Location Map


Attachment 1. Sample Descriptions

Attachment 2

On-site workers

ID = C X IR X ER X 10-6
BW

Where EF = Exposure Frequency X Exposure Duration/Exposure Time

= (5 days/week)(50 weeks/year)(30 years)
365 days/year (70 years)

= 0.29


ID = (Concentration)(100 mg/day)(0.29) X 10-6
70 kg

IDs = Concentration (4.14 X 10-7) for workers

Children

ID = C X IR X EF X 10-6/BW

EF = (7 days/week)(52 weeks/year)(10 years)
(365 days/year)(10 years)

= 1.0

ID = Concentration (100 mg/day)(1.0) X 10-6
10 kg

Residential Child Exposure

= 1.0 X 10-5 (Concentration)


CERTIFICATION

This Certain-teed Corporation Site Health Consultation was prepared by the Illinois Department of Public Healthunder a cooperative agreement with the Agency for Toxic Substances and Disease Registry (ATSDR). It is inaccordance with approved methodology and procedures existing at the time the health consultation was begun.

Gail D. Godfrey
Technical Project Officer
Division of Health Assessment and Consultation
ATSDR

The Division of Health Assessment and Consultation, ATSDR, has reviewed this health consultation and concurs with its findings.

Richard E. Gillig
Chief, State Programs Section
Division of Health Assessment and Consultation
ATSDR


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