LOWER ECORSE CREEK DUMP
WYANDOTTE, WAYNE COUNTY, MICHIGAN
APPENDIX A.
FIGURES
LIST OF FIGURES

Figure 1. Location of Lower Ecorse River Dump Site
LIST OF TABLES
| Chemical | Date | Maximum Concentration (ppm) | Reference | Comparison Value (ppm) |
| arsenic | 1/94 | 17.2 | 9 | 0.6E, 0.4C |
| barium | 1/94 | 238 | 9 | 100R |
| benzo(a)anthracene | 1/94 | 2.6 | 9 | carcinogen |
| benzo(a)pyrene | 1/94 | 2.4 | 9 | 0.1C |
| benzo(b)fluoranthene | 1/94 | 3.7 | 9 | carcinogen |
| cadmium | 1/94 | 2.4 | 9 | 1E, carcinogen |
| chromium | 1/94 | 612 | 9 | 2,000R (III) carcinogen (VI) |
| chrysene | 1/94 | 2.7 | 9 | carcinogen |
| copper | 1/94 | 1,510 | 9 | NA |
| cyanide (total) | 10/89 | 5,800 | 9 | 40R |
| 12/92 | 1,920 | 9 | ||
| 1/94 | 2,240 | 9 | ||
| (WAD) | 12/92 | 288 | 9 | |
| 1/94 | 401 | 9 | ||
| fluoranthene | 1/94 | 5.4 | 9 | 80R |
| lead | 1/94 | 316 | 9 | carcinogen |
| mercury | 1/94 | 1.4 | 9 | NA |
| phenanthrene | 1/94 | 5.1 | 9 | NA |
| pyrene | 1/94 | 5.8 | 9 | 60R |
| zinc | 1/94 | 5,650 | 9 | 600R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
WAD Weak Acid Dissociated cyanide
NA None Available
Comparison Value Bases
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
E ATSDR Environmental Media Evaluation Guides (EMEGs)
R ATSDR Reference Dose Media Evaluation Guides (RMEGs), calculated from U.S. EPA Reference Dose,
assuming child ingestion, pica behavior
C ATSDR Cancer Risk Evaluation Guides (CREGs), for 1 x 10-6 estimated excess cancer risk (a significant
additional risk of developing cancer is taken to be one additional case of cancer in a population of 1 million people
experiencing the exposure)
| Chemical | Date | Maximum Concentration (ppm) | Reference | Comparison Value (ppm) |
| arsenic | 1/94 | 27.3 | 9 | 0.6E, 0.4C |
| 11/94 | 6.1 | 4 | ||
| barium | 1/94 | 776 | 9 | 100R |
| 11/94 | 65.7 | 4 | ||
| benzo(a)anthracene | 1/94 | 60 | 9 | carcinogen |
| 11/94 | 0.16J | 4 | ||
| benzo(a)pyrene | 1/94 | 52 | 9 | 0.1C |
| 11/94 | 0.16J | 4 | ||
| benzo(b)fluoranthene | 1/94 | 72 | 9 | carcinogen |
| 11/94 | 0.37J(7) | 4 | ||
| cadmium | 1/94 | 9.9 | 9 | 1E, carcinogen |
| 11/94 | 0.48J | 4 | ||
| chromium | 1/94 | 1,610 | 9 | 2,000R (III) carcinogen (VI) |
| 11/94 | 16.8J | 4 | ||
| chrysene | 1/94 | 84 | 9 | carcinogen |
| 11/94 | 0.15J | 4 | ||
| copper | 1/94 | 455 | 9 | NA |
| 11/94 | 16.9 | 4 | ||
| cyanide (total) | 10/89 | 31.6 | 9 | 40R |
| 4/90 | 408 | 9 | ||
| 5/91 | 2,460 | 9 | ||
| 10/91 | 190 | 9 | ||
| 6/92 | 13,440 | 9 | ||
| 4/93 | 990 | 9 | ||
| 1/94 | 32,300 | 9 | ||
| 11/94 | 2.1 | 4 | ||
| (WAD) | 6/92 | 1,262 | 9 | |
| 4/93 | 840 | 9 | ||
| 1/94 | 679 | 9 | ||
| fluoranthene | 1/94 | 150 | 9 | 80R |
| 11/94 | 0.29J | 4 | ||
| lead | 1/94 | 8,310 | 9 | carcinogen |
| 11/94 | 52.J | 4 | ||
| mercury | 1/94 | 8.8 | 9 | NA |
| 11/94 | ND (0.11) | 4 | ||
| 2-methylnaphthalene | 1/94 | 9.6 | 9 | NA |
| 11/94 | ND (0.38) | 4 | ||
| naphthalene | 1/94 | 14 | 9 | NA |
| 11/94 | ND (0.38) | 4 | ||
| phenanthrene | 1/94 | 94 | 9 | NA |
| 11/94 | 0.12J | 4 | ||
| pyrene | 1/94 | 120 | 9 | 60R |
| 11/94 | 0.3J | 4 | ||
| selenium | 1/94 | 5.8 | 9 | 4E |
| 11/94 | 0.41J | 4 | ||
| silver | 1/94 | 12.7 | 9 | 10R |
| 11/94 | 0.13J | 4 | ||
| zinc | 1/94 | 1,090 | 9 | 600R |
| 11/94 | 111.J | 4 |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
WAD Weak Acid Dissociated cyanide
ND Not Detected (with detection limit)
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available
Comparison Value Bases
R ATSDR Reference Dose Media Evaluation Guides (RMEGs), calculated from U.S. EPA Reference Dose,
assuming child ingestion, pica behavior
C ATSDR Cancer Risk Evaluation Guides (CREGs), for 1 x 10-6 estimated excess cancer risk (a significant additional risk of developing cancer is taken to be one additional case of cancer in a population of 1 million people experiencing the exposure)
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
E ATSDR Environmental Media Evaluation Guides (EMEGs)
| Date | Sample Type | Maximum Concentration (ppb) | Reference |
| 10/89 | sump water | 2,400 | 9 |
| 4/90 | groundwater | 229,500 | 9 |
| 5/91 | sump water | 5,000 | 9 |
| 6/91 | sump water | 700 | 9 |
| 10/91 | sump water | 1,000 | 9 |
| 6/92 | sump water | 1,200. (total) | 9 |
| 400. (WAD) | 9 | ||
| 1/93 | sump water | 12,000. (total) | 9 |
| 1,400. (WAD) | 9 | ||
| 4/93 | sump water | 10,000. (total) | 9 |
| 1,100. (WAD) | 9 | ||
| water | 72,000. (total) | 9 | |
| 25,000. (WAD) | 9 | ||
| 12/94 | basement water | 5,150. (total) | 4 |
WAD Weak Acid Dissociable cyanide
Comparison Value: 200 ppb (RMEG)
| Chemical | Date | Maximum Concentration (ppb) | Reference | Comparison Value (ppb) |
| arsenic | 12/94 | 1.8J | 4 | 3E, 0.02C |
| barium | 12/94 | 63.4 | 4 | 700R |
| cobalt | 12/94 | 1.7J | 4 | NA |
| copper | 12/94 | 7.4J | 4 | 1,300MCLG |
| cyanide (total) | 12/94 | 5,150 | 4 | 200R |
| lead | 12/94 | 2.9J | 4 | 15PL, carcinogen |
| manganese | 12/94 | 51.3 | 4 | 50R |
| vanadium | 12/94 | 0.98J | 4 | 30iE |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available Comparison Value Bases
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
E ATSDR Environmental Media Evaluation Guides (EMEGs)
iE ATSDR Environmental Media Evaluation Guides (EMEGs), intermediate exposure duration
R ATSDR Reference Dose Media Evaluation Guides (RMEGs), calculated from U.S. EPA Reference Dose,
assuming child ingestion
C ATSDR Cancer Risk Evaluation Guides (CREGs), for 1 x 10-6 estimated excess cancer risk (a significant
additional risk of developing cancer is taken to be one additional case of cancer in a population of 1 million people
experiencing the exposure)
A U.S. EPA Drinking Water Lifetime Health Advisory
MCLG U.S. EPA Safe Drinking Water Act Maximum Contaminant Level Goal
PL U.S. EPA Proposed Action Level for Lead in Drinking Water
| Chemical | Date | Maximum Concentration (ppm) | Reference | Comparison Value (ppm) |
| antimony | 12/94 | 6.5J | 4 | 0.8R |
| arsenic | 12/94 | 5.5J | 4 | 0.6E, 0.4C |
| barium | 12/94 | 177 | 4 | 100R |
| beryllium | 12/94 | 0.26J | 4 | 10R, 0.2C |
| cadmium | 12/94 | 5.8J | 4 | 1E, carcinogen |
| chromium | 12/94 | 68.1J | 4 | 2,000R (III) carcinogen (VI) |
| cobalt | 12/94 | 6.J | 4 | NA |
| copper | 12/94 | 1,180.J | 4 | NA |
| cyanide (total) | 12/94 | 0.74J | 4 | 40R |
| lead | 12/94 | 1,570.J | 4 | carcinogen |
| manganese | 12/94 | 1,220.J | 4 | 300R |
| mercury | 12/94 | 1.1 | 4 | NA |
| nickel | 12/94 | 243.J | 4 | carcinogen |
| silver | 12/94 | 1.1J | 4 | 10R |
| vanadium | 12/94 | 11.5 | 4 | 6iE |
| zinc | 12/94 | 1,210.J | 4 | 600R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available
Comparison Value Bases
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
E ATSDR Environmental Media Evaluation Guides (EMEGs)
iE ATSDR Environmental Media Evaluation Guides (EMEGs), intermediate exposure duration
R ATSDR Reference Dose Media Evaluation Guides (RMEGs), calculated from U.S. EPA Reference Dose,
assuming child ingestion, pica behavior
C ATSDR Cancer Risk Evaluation Guides (CREGs), for 1 x 10-6 estimated excess cancer risk (a significant
additional risk of developing cancer is taken to be one additional case of cancer in a population of 1 million people
experiencing the exposure)
| Chemical | Date | Maximum Concentration (ppm) | Reference | Comparison Value (ppm) |
| acenaphthylene | 11/94 | 0.55J | 4 | NA |
| antimony | 11/94 | 2.7J | 4 | 0.8R |
| arsenic | 11/94 | 30.6 | 4 | 0.6E, 0.4C |
| barium | 11/94 | 717 | 4 | 100R |
| benzo(a)anthracene | 11/94 | 13 | 4 | carcinogen |
| benzo(a)pyrene | 11/94 | 9.2 | 4 | 0.1C |
| benzo(b)fluoranthene | 11/94 | 8.8 | 4 | carcinogen |
| 15.(8) | ||||
| benzo(g,h,i)perylene | 11/94 | 2.5 | 4 | NA |
| benzo(k)fluoranthene | 11/94 | 3.9 | 4 | carcinogen |
| 15.(8) | ||||
| beryllium | 11/94 | 0.97 | 4 | 10R, 0.2C |
| bis(2-ethylhexyl)phthalate | 11/94 | 4.8J | 4 | 40R, 50C |
| cadmium | 11/94 | 6.9 | 4 | 1E, carcinogen |
| chromium | 11/94 | 684.J | 4 | 2,000R (III) carcinogen (VI) |
| chrysene | 11/94 | 13 | 4 | carcinogen |
| cobalt | 11/94 | 14.6 | 4 | NA |
| copper | 11/94 | 583 | 4 | NA |
| cyanide (total) | 11/94 | 4 | 4 | 40R |
| dibenzo(a,h)anthracene | 11/94 | 0.9J | 4 | carcinogen |
| fluoranthene | 11/94 | 10 | 4 | 80R |
| indeno(1,2,3-cd)pyrene | 11/94 | 3 | 4 | carcinogen |
| lead | 11/94 | 737.J | 4 | carcinogen |
| manganese | 11/94 | 15,000.J | 4 | 300R |
| mercury | 11/94 | 0.88 | 4 | NA |
| 2-methylnaphthalene | 11/94 | 0.68J | 4 | NA |
| naphthalene | 11/94 | 0.84 | 4 | NA |
| nickel | 11/94 | 80.4 | 4 | carcinogen |
| phenanthrene | 11/94 | 7.8 | 4 | NA |
| polychlorinated biphenyls (PCBs) | 11/94 | 0.25J | 4 | 0.04E, 0.09C |
| pyrene | 11/94 | 23 | 4 | 60R |
| selenium | 11/94 | 4.1J | 4 | 4E |
| silver | 11/94 | 2.5 | 4 | 10R |
| thallium | 11/94 | 1.4J | 4 | NA |
| vanadium | 11/94 | 136 | 4 | 6iE |
| zinc | 11/94 | 908 | 4 | 600R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available Comparison Value Bases
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
E ATSDR Environmental Media Evaluation Guides (EMEGs)
iE ATSDR Environmental Media Evaluation Guides (EMEGs), intermediate exposure duration
R ATSDR Reference Dose Media Evaluation Guides (RMEGs), calculated from U.S. EPA Reference Dose,
assuming child ingestion, pica behavior
C ATSDR Cancer Risk Evaluation Guides (CREGs), for 1 x 10-6 estimated excess cancer risk (a significant
additional risk of developing cancer is taken to be one additional case of cancer in a population of 1 million people
experiencing the exposure)
| Chemical | Date | Maximum Concentration (ppb) | Reference | Comparison Value (ppb) |
| arsenic | 12/94 | 19.6 | 4 | 3E, 0.02C |
| barium | 12/94 | 53.3J | 4 | 700R |
| beryllium | 12/94 | 0.1J | 4 | 50R, 0.008C |
| bis(2-ethylhexyl)phthalate | 12/94 | 140.J | 4 | 200R, 3C |
| butyl benzyl phthalate | 12/94 | 15.J | 4 | 2,000R, carcinogen |
| cadmium | 12/94 | 11.3 | 4 | 7E, carcinogen |
| chromium | 12/94 | 36.1 | 4 | 10,000R (III) 50R, carcinogen (VI) |
| cobalt | 12/94 | 11.6J | 4 | NA |
| copper | 12/94 | 5,740 | 4 | 1,300MCLG |
| cyanide (total) | 12/94 | 14.4 | 4 | 200R |
| di-n-octyl phthalate | 12/94 | 78.J | 4 | NA |
| lead | 12/94 | 125 | 4 | 15PL, carcinogen |
| manganese | 12/94 | 632 | 4 | 50R |
| mercury 4-methylphenol | 12/94 | 141 13 | 4 | 2A carcinogen |
| nickel | 12/94 | 906 | 4 | 100A, carcinogen |
| phenanthrene | 12/94 | 17.J | 4 | NA |
| selenium | 12/94 | 14.1 | 4 | 20E |
| silver | 12/94 | 2.4J | 4 | 50R |
| vanadium | 12/94 | 16.4J | 4 | 30iE |
| zinc | 12/94 | 26,500.J | 4 | 3,000R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available Comparison Value Bases
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
E ATSDR Environmental Media Evaluation Guides (EMEGs)
iE ATSDR Environmental Media Evaluation Guides (EMEGs), intermediate exposure duration
R ATSDR Reference Dose Media Evaluation Guides (RMEGs), calculated from U.S. EPA Reference Dose,
assuming child ingestion
C ATSDR Cancer Risk Evaluation Guides (CREGs), for 1 x 10-6 estimated excess cancer risk (a significant
additional risk of developing cancer is taken to be one additional case of cancer in a population of 1 million people experiencing the exposure)
A U.S. EPA Drinking Water Lifetime Health Advisory
MCLG U.S. EPA Safe Drinking Water Act Maximum Contaminant Level Goal
PL U.S. EPA Proposed Action Level for Lead in Drinking Water
| Chemical | Date | Maximum Concentration (ppm) | Reference | Comparison Value (ppm) |
| antimony | 12/94 | 0.68J | 4 | 0.8R |
| arsenic | 12/94 | 6.7J | 4 | 0.6E, 0.4C |
| barium | 12/94 | 111 | 4 | 100R |
| beryllium | 12/94 | 0.61J | 4 | 10R, 0.2C |
| cadmium | 12/94 | 1.4 | 4 | 1E, carcinogen |
| chromium | 12/94 | 24.2J | 4 | 2,000R (III) carcinogen (VI) |
| cobalt | 12/94 | 9.5 | 4 | NA |
| copper | 12/94 | 297 | 4 | NA |
| cyanide (total) | 12/94 | 0.61J | 4 | 40R |
| lead | 12/94 | 255.J | 4 | carcinogen |
| manganese | 12/94 | 1,420.J | 4 | 300R |
| mercury | 12/94 | 0.19 | 4 | NA |
| nickel | 12/94 | 26.2J | 4 | carcinogen |
| selenium | 12/94 | 1.1J | 4 | 4E |
| silver | 12/94 | 0.67J | 4 | 10R |
| vanadium | 12/94 | 25.1 | 4 | 6iE |
| zinc | 12/94 | 717.J | 4 | 600R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
Comparison Value Bases
| Chemical | Date | Maximum Concentration (ppb) | Reference | Comparison Value (ppb) |
| arsenic | 11/94 | 5.6J | 4 | 3E, 0.02C |
| barium | 12/94 | 265 | 4 | 700R |
| cobalt | 12/94 | 1.6J | 4 | NA |
| copper | 12/94 | 0.87J | 4 | 1,300MCLG |
| cyanide (total) | 12/94 | 31.4 | 4 | 200R |
| manganese | 12/94 | 1,420 | 4 | 50R |
| nickel | 12/94 | 4.2J | 4 | 100A, carcinogen |
| selenium | 12/94 | 14.1 | 4 | 20E |
| thallium | 12/94 | 11.9J | 4 | 0.4A |
| vanadium | 12/94 | 2.5J | 4 | 30iE |
| zinc | 12/94 | 2.4J | 4 | 3,000R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
Comparison Value Bases
| Chemical | Date | Maximum Concentration (ppb) | Reference | Comparison Value (ppb) | |||
| Upstream | At Site | Downstream | |||||
| S. Br. | N. Br. | ||||||
| arsenic | 12/94 | 3.0J | 2.5J | 2.J | 2.J | 4 | 3E, 0.02C |
| barium | 12/94 | 93.4J | 108.J | 86.6J | 88.4J | 4 | 700R |
| benzene | 12/94 | ND (10) | ND (10) | 2.J | ND (10) | 4 | 30R, 1C |
| beryllium | 12/94 | ND (0.1) | ND (0.1) | ND (0.1) | 0.11J | 4 | 50R, 0.008C |
| cadmium | 12/94 | 0.76J | 1.7J | 0.85J | 0.70J | 4 | 7E, carcinogen |
| chromium | 12/94 | 10.9 | 19.3 | 10.4 | 11.6 | 4 | 10,000R (III) 50R, carcinogen (VI) |
| cobalt | 12/94 | 1.5J | 1.6J | 0.58J | 1.4J | 4 | NA |
| copper | 12/94 | 14.9J | 27.1 | 11.7J | 14.J | 4 | 1,300MCLG |
| cyanide (total) | 12/94 | 18.8J | 20.8J | 22.8J | 20.4 | 4 | 200R |
| lead | 12/94 | 22.4 | 57.8 | 19.8 | 23.3 | 4 | 15PL, carcinogen |
| manganese | 12/94 | 178 | 221 | 156 | 154 | 4 | 50R |
| nickel | 12/94 | ND (6.6) | 8.2J | ND (5) | ND (5.6) | 4 | 100A, carcinogen |
| vanadium | 12/94 | 7.9J | 9.8J | 5.J | 7.2J | 4 | 30iE |
| zinc | 12/94 | ND (86.5) | 211.J | 106.J | 114.J | 4 | 3,000R |
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
Comparison Value Bases
| Chemical | Maximum Concentration (ppm) | Comparison Value (ppm) | ||||
| Upstream | At Site | Downstream | Seep | |||
| S. Br. | N. Br. | |||||
| acenaphthylene | ND (1) | ND (0.92) | ND (1) | 0.091J | ND (0.42) | NA |
| antimony | 0.68J | 1.3J | 0.74J | 0.96J | 0.97J | 0.8R |
| arsenic | 12.6J | 8.9J | 11.2J | 10.1J | 10.6 | 0.6E, 0.4C |
| barium | 186 | 217 | 162 | 181 | 202 | 100R |
| benzo(a)anthracene | 0.71J | 0.63J | 0.92J | 1.2 | 0.64 | carcinogen |
| benzo(a)pyrene | 0.73J | 0.64J | 0.8J | 1.1J | 0.6 | 0.1C |
| benzo(b)fluoranthene | 1.5J | 0.49J | 1.2J | 1.7J | 2.1(9) | carcinogen |
| benzo(g,h,i)perylene | 0.18J | 0.17J | 0.25J | 0.39J | 0.11J | NA |
| benzo(k)fluoranthene | 1.J | 1.4 | 2.J | 2.J | 2.1(9) | carcinogen |
| beryllium | 0.93J | 0.62J | 0.81J | 0.89J | 0.76J | 10R, 0.2C |
| butyl benzyl phthalate | 0.21J | 0.14J | 0.24J | 0.43J | | 400R, carcinogen |
| cadmium | 2.7J | 3.7J | 4.6J | 4.4J | 2.3 | 1E, carcinogen |
| carbazole | 0.13J | 0.12J | 0.16J | 0.2J | | NA |
| chromium | 70.9J | 120.J | 72.7J | 79.7J | 49.8J | 2,000R (III) carcinogen (VI) |
| chrysene | 1.2 | 0.86J | 1.1 | 1.6J | 0.64 | carcinogen |
| cobalt | 11.6J | 6.6J | 9.6J | 10.J | 8.3J | NA |
| copper | 108.J | 107.J | 115.J | 151 | 119.J | NA |
| cyanide (total) | ND (0.37) | 0.49 | 0.45 | 0.66 | ND (0.62) | 40R |
| dibenzo(a,h)anthracene | 0.19J | 0.14J | 0.2J | 0.34J | 0.048J | carcinogen |
| di-n-octyl phthalate | 0.29J | 0.21J | 0.54J | 0.56J | | NA |
| fluoranthene | 1.9 | 1.8 | 2.3 | 2.9 | 1.4 | 80R |
| indeno(1,2,3-cd)pyrene | 0.38J | 0.29J | 0.51J | 0.73J | 0.25J | carcinogen |
| lead | 205.J | 625.J | 230.J | 283.J | 205.J | carcinogen |
| manganese | 676 | 515 | 662 | 616 | 285.J | 300R |
| mercury | 8.9 | 1.7 | 0.38 | 0.6 | 0.61 | NA |
| nickel | 36.6J | 26.9J | 31.8J | 35.3J | 29.6 | carcinogen |
| phenanthrene | 1 | 0.76J | 0.89J | 1.3 | 0.64J | NA |
| pyrene | 2.5 | 1.6 | 2.4 | 3.6J | 1 | 60R |
| selenium | 1.8J | 1.7J | 2.4J | 1.5J | 1.3J | 4E |
| silver | 1.3J | 2.4 | 1.0J | 1.8J | 2.9J | 10R |
| vanadium | 46.2 | 29.7 | 38.1 | 41.6 | 41.4 | 6iE |
| zinc | 582.J | 685.J | 661.J | 665.J | 457.J | 600R |
Reference: 4
Chemicals not detected are not listed.
Bolded chemicals exceed comparison values.
ND Not Detected (with detection limit)
= Analyses not reported
J Estimated Value. Chemical detected at level below Contract Required Detection Level.
NA None Available
carcinogen Carcinogen (proven, probable, or possible) but no CREG available
Comparison Value Bases
References: 12, 13, 14, 15, 16
Sampling locations shown on Figure 1.
MDNR Michigan Department of Natural Resources
OMOE Ontario Ministry of the Environment
PCBs Polychlorinated biphenyls
PAHs Polycyclic aromatic hydrocarbons
| Chemical | Date | Sample Type(10) | Maximum Concentration (ppm) | Reference | MDPH Level of Concern(11) (ppm) | ||
| Carp | Walleye | Freshwater Drum | |||||
| chlordane (total) | 1981 | NR | | 0.022 | 0.022 | 12 | 0.3 |
| 1985 | fillet | 0.26 | | | 13 | ||
| 1986 | NR | 0.15 | 0.004 | ND (0.002) | 12 | ||
| 1990 | fillet | 0.037 | | | 12 | ||
| fillet | 0.093 | 0.045 | 0.036 | 15 | |||
| whole | 0.158 | 0.177 | | 15 | |||
| 1992 | whole | 0.294 | 0.249 | | 16 | ||
| copper | 1985 | fillet | 2.2 | | | 13 | 10-100(12) |
| 1986 | fillet | 1 | 0.8 | | 14 | ||
| 4,4'-DDD | 1981 | NR | | 0.038 | 0.025 | 12 | 5.0(13) |
| 1985 | fillet | 0.314 | | | 13 | ||
| 1986 | NR | 0.992 | 0.009 | ND (0.002) | 12 | ||
| 1990 | fillet | 0.083 | | | 12 | ||
| fillet | 0.171 | 0.04 | 0.041 | 15 | |||
| whole | 0.206 | 0.076 | | 15 | |||
| 1992 | whole | 0.237 | 0.117 | | 16 | ||
| 4,4'-DDE | 1981 | NR | | 0.017 | 0.041 | 12 | |
| 1985 | fillet | 0.80 | | | 13 | ||
| 1986 | NR | 0.521 | 0.028 | 0.012 | 12 | ||
| 1990 | fillet | 0.722 | | | 12 | ||
| fillet | 0.884 | 0.153 | 0.059 | 15 | |||
| whole | 0.814 | 0.407 | | 15 | |||
| 1992 | whole | 0.832 | 0.463 | | 16 | ||
| 4,4'-DDT | 1981 | NR | | 0.032 | 0.012 | 12 | |
| 1985 | fillet | 0.005 | | | 13 | ||
| 1986 | NR | 0.035 | 0.006 | ND (0.002) | 12 | ||
| 1990 | fillet | ND (0.005) | | | 12 | ||
| fillet | 0.036 | 0.011 | 0.019 | 15 | |||
| whole | 0.027 | 0.025 | | 15 | |||
| 1992 | whole | 0.017 | 0.032 | | 16 | ||
| dieldrin | 1985 | fillet | 0.030 | | | 13 | 0.3 |
| 1990 | fillet | 0.045 | 0.011 | 0.01 | 15 | ||
| whole | 0.048 | 0.035 | | 15 | |||
| 1992 | whole | 0.040 | 0.041 | | 16 | ||
| dioxins and furans (total) (2,3,7,8-TCDD equivalents) | 1990 | fillet | 135.1 ppt | | | 12 | 10 ppt (2,3,7,8-TCDD equivalents) |
| 1990 | fillet | 11.71 ppt | | | 12 | ||
| heptachlor epoxide | 1985 | fillet | 0.022 | | | 13 | 0.3 |
| 1990 | fillet | 0.007 | 0.004 | 0.006 | 15 | ||
| whole | 0.01 | 0.009 | | 15 | |||
| 1992 | whole | 0.015 | 0.016 | | 16 | ||
| hexachlorobenzene | 1981 | NR | | 0.005 | 0.043 | 12 | 0.2-0.5(12) |
| 1985 | fillet | 0.092 | | | 13 | ||
| 1986 | NR | 0.063 | 0.005 | 0.004 | 12 | ||
| 1990 | fillet | 0.023 | | | 12 | ||
| fillet | 0.019 | 0.01 | 0.011 | 15 | |||
| whole | 0.02 | 0.023 | | 15 | |||
| 1992 | whole | 0.013 | 0.008 | | 16 | ||
| lead | 1985 | fillet | 1.1 | | | 13 | 0.5-10(12) |
| 1986 | fillet | 0.115 | ND (0.1) | | 14 | ||
| mercury | 1981 | NR | | 0.39 | 0.84 | 12 | 0.5 |
| 1985 | fillet | 0.4 | | | 13 | ||
| 1986 | NR | 0.17 | 0.32 | 1.1 | 12 | ||
| fillet | 0.45 | 0.79 | | 14 | |||
| 1990 | fillet | 0.59 | | | 12 | ||
| fillet | 0.18 | 0.29 | 0.82 | 15 | |||
| whole | 0.18 | 0.32 | | 15 | |||
| 1992 | whole | 0.16 | 0.44 | | 16 | ||
| nickel | 1985 | fillet | 1.9 | | | 13 | NA |
| 1986 | fillet | 0.15 | 0.104 | | 14 | ||
| octachlorostyrene | 1981 | NR | | 0.014 | 0.028 | 12 | NA |
| 1986 | NR | 0.076 | 0.01 | 0.003 | 12 | ||
| 1990 | fillet | 0.053 | | | 12 | ||
| fillet | 0.021 | 0.005 | 0.005 | 15 | |||
| whole | 0.048 | 0.129 | | 15 | |||
| 1992 | whole | 0.038 | 0.032 | | 16 | ||
| PCBs (total) | 1981 | NR | | 0.611 | 1.274 | 12 | 2.0 |
| NR | 31 | | | 13 | |||
| 1985 | fillet | 25.6 | | | 13 | ||
| 1986 | NR | 9.73 | 0.395 | 0.301 | 12 | ||
| fillet | 23.52 | 2.567 | | 14 | |||
| 1990 | fillet | 4.29 | | | 12 | ||
| fillet | 33.929 | 3.195 | 2.277 | 15 | |||
| whole | 7.794 | 2.926 | | 15 | |||
| 1992 | whole | 13.19 | 5.5 | | 16 | ||
| phenanthrene | 1990 | fillet | 0.311 | | | 12 | NA |
| zinc | 1985 | fillet | 20 | | | 13 | 30-1,000(12) |
| 1986 | fillet | 48 | 10 | | 14 | ||
ND Not Detected (with detection limit)
= Species not sampled or analyses not reported
NR Sample Type not reported
1981, 1986, 1990 (Ref. 12) data from Ontario, collected at Fighting Island (see Figure 1). Other data from MDNR collections, locations listed in Table 12.
| Chemical | Date | Maximum Concentration (ppm) | MDPH Level of Concern(14) (ppm) | ||
| Rock Bass | White Bass | Northern Pike | |||
| chlordane (total) | 1981 | 0.039 | 0.046 | | 0.3 |
| 1986 | 0.003 | 0.044 | ND (0.002) | ||
| 4,4'-DDD | 1981 | 0.048 | 0.058 | | 5.0(15) |
| 1986 | 0.021 | 0.118 | 0.005 | ||
| 4,4'-DDE | 1981 | 0.047 | 0.070 | | |
| 1986 | 0.276 | 0.162 | 0.003 | ||
| 4,4'-DDT | 1981 | 0.017 | 0.027 | | |
| 1986 | 0.037 | 0.035 | ND (0.002) | ||
| hexachlorobenzene | 1981 | 0.027 | 0.017 | | 0.2-0.5(16) |
| 1986 | 0.003 | 0.009 | 0.003 | ||
| mercury | 1981 | 0.97 | 0.58 | | 0.5 |
| 1986 | 0.53 | 0.42 | 0.30 | ||
| octachlorostyrene | 1981 | 0.046 | 0.061 | | NA |
| 1986 | 0.025 | 0.013 | 0.005 | ||
| PCBs (total) | 1981 | 1.637 | 2.386 | | 2.0 |
| 1986 | 0.622 | 2.920 | 0.274 | ||
Reference: 12
ND Not Detected (with detection limit)
= Species not sampled or analyses not reported
NR Sample Type not reported
| Sample | Bioavailable (ppm) | WAD (ppm) | Total (ppm) |
| A | 7.6 | 214 | 3,487 |
| B | 24.8 | 636 | 7,777 |
| C | 3.3 | 96 | 853 |
| D | 5.4 | 38 | 50 |
| E | 7.2 | 116 | 2,870 |
Reference 22, Table 14
Sample types and sample locations are not available.
Comparison Value: 40 ppm (RMEG)
| Contaminated material Population | Total | WAD | Bioavailable(17) | |
| surface soil | ||||
| child (pica) | >LDLO | >RfD | <RfD | |
| child (incidental) | >RfD | <RfD | <RfD | |
| adult (incidental) | <RfD | <RfD | <RfD | |
| subsurface soil | ||||
| child (pica) | >LDLO | >LDLO | >RfD | |
| child (incidental) | >LDLO | >RfD | <RfD | |
| adult (incidental) | >RfD | <RfD | <RfD | |
LDLO Lowest Observed Lethal Dose in humans (from Reference 10)
RfD U.S. EPA Reference Dose (chronic)
WAD Weak Acid Dissociated cyanide
> = Ingestion exposure might exceed standard (but not likely to exceed next higher standard)
< = Ingestion exposure is not likely to exceed standard
The MDPH released a draft of this Public Health Assessment for public comment on March 1, 1995. The comment period lasted until March 31, 1995, and was extended to April 15, 1995, at the request of an area resident. Comments received are addressed below.
Response: We understand your feelings about the word "dump" in the name used for the site. We do not name Superfund sites, but are required to use the names under which the sites are officially listed on the National Priorities List. Earlier, the site in your neighborhood was called the Wyandotte Cyanide site and then the North Drive site. The "Lower Ecorse Creek Dump site" has become the "official" name of the site, despite the unfortunate connotations for your neighborhood.
Response: We have clarified and simplified some of the more technical language for the final release of the assessment.
Response: Our understanding is that the reason the tree was moved was not for the purpose of avoiding the contamination. The mention in the assessment was merely to provide anecdotal evidence that the blue material does migrate into plants.
Response: The prevailing winds throughout Michigan are from the west to southwest, though wind may blow from any direction at any given time. At the section of the assessment you mentioned, the assessors used the prevailing wind direction to evaluate the possible impact on the site from nearby facilities that reported to the U.S. EPA's Toxic Chemical Release Inventory (TRI) that they released chemicals to the air. Since the primary exposed population lives on the site, which is not downwind of these facilities in most weather conditions, we think it very unlikely that these additional potential sources of exposure contribute to the exposure of those people on the site.
Response: No animals or birds from the area have been sampled and analyzed. We have been unable to find any reports of unusual numbers of dead birds or animals in the site area.
Response: In December 1994, a contractor for the U.S. EPA collected eight soil samples from the north bank of the Lower Ecorse River across from the site. Two of these samples contained cyanide, but at low concentrations (0.32 and 0.35 parts per million [ppm], ATSDR's comparison value for cyanide in soil is 40 ppm), comparable to that found in background soils (4, 24). This does not indicate that any contamination related to the site has reached the north bank of the river.
Response: The soil cover was not intended to be the ultimate solution, but as a temporary remedy while a more permanent solution was developed. Enough soil was indeed applied to compact to a stable six-inch-thick layer.
Response: The coating is designed to seal the concrete and prevent water from seeping through cracks and pores in the basement walls. The chemical resistance was designed into the coating to prevent or slow down attacks on the coating by the chemicals in the water.
Response: The intake pipe for the Detroit water system does come ashore at that point. However, to minimize the impact of onshore pollution sources on the water brought into the municipal system, the actual intake, the drawing end of the pipe, is located in the middle of the river, approximately 1 mile from the Michigan shore.
Response: CERCLIS is an acronym for the Comprehensive Environmental Response, Compensation, and Liability Act Information System. The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980, as amended, is the formal title of the act that set up the Superfund program. CERCLIS is a database of places and incidents of environmental contamination maintained by the U.S. EPA. The National Priorities List, commonly called the Superfund list, is a subset of sites on CERCLIS that meet certain specifications.
Response: From our review of the sampling data, we do not believe that there is sufficient information available to agree or disagree with your conclusion. The apparent increase may be due to changes in sampling methods or locations rather than any increase over time.
Response: We share your concern.
Response: We recognize your concerns, but do not agree with your conclusion. We believe that exposure can be prevented without such methods.
1.
Pica behavior is an abnormal consumption of non-food materials, such as soil, most often seen in children under 5 years of age.2.
From the sample numbers in the data sheets (9), not all samples were analyzed for the complete suite of analytes. There is no information available on the reasons for their selection.3.
Of the standard analysis techniques for cyanide, Weak Acid Dissociable (WAD) cyanide analysis is considered to more accurately represent the biologically available cyanide present than total cyanide analysis. The WAD analysis measures the amount of cyanide in the sample that would be likely to dissolve under conditions in the stomach and absorbed by the intestine.4.
ATSDR prefers surface soil samples to be no more than 3 inches deep to accurately reflect the conditions people are likely to come into contact with.5.
See note 4, page 7.6.
Assuming that the total cyanide detected is free cyanide. The cyanide in the soil at the site is in an iron complex which binds the cyanide ion tightly so it is less likely to cause health effects than free cyanide.7.
Combined benzo(b)fluoranthene and benzo(k)fluoranthene.8.
Combined benzo(b)fluoranthene and benzo(k)fluoranthene.9.
Combined benzo(b)fluoranthene and benzo(k)fluoranthene.10.
Fillets are skinless for carp, with skin on for other species.11.
MDPH uses FDA Action Levels, except for mercury (FDA 1 ppm) and dioxins (FDA 25 ppt 2,3,7,8-TCDD equivalents).12.
International range of legal limits in fish (17). No MDPH or U.S. FDA Level of Concern.13.
Total DDT, DDD, and DDE.14.
MDPH uses FDA Action Levels, except for mercury (FDA 1 ppm).15.
Total DDT, DDD, and DDE.16.
International range of legal limits in fish (17). No MDPH or U.S. FDA Level of Concern.17.
Calculated after Ref. 22